Cleave is a surname. Notable people with the surname include:
- Chris Cleave (born 1973), British journalist
- Egbert Cleave (fl. 1870s), American author
- John Cleave (born c. 1790), British chartist
- Mary L. Cleave (born 1947), American astronaut and engineer
- Maureen Cleave (1934-2021), British journalist
- Paul Cleave (born 1974), New Zealand author
- Thomas L. Cleave (1906-1983), British surgeon captain
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