The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I−). They are in the class of mixed anion compounds or chalcogenide halides.[1]
Tellurium does not normally bond with iodine, but can form many different units with bonds to other tellurium atoms.
List
name | formula | system | space group | unit cell | volume | density | properties | ref |
---|---|---|---|---|---|---|---|---|
Copper telluride iodide | CuTeI | tetrahedral | I41/amd | a = 17.170, c = 4.876, and Z = 16 | Cu+1 ion conductor; metallic grey | [2][3] | ||
(CuI)3Cu2TeS3 | P3121 | [1] | ||||||
gallium telluride iodide | GaTeI | orthorhombic | band gap 2.55 | [1] | ||||
Ge40.0Te5.3I8 | cubic | Pm3n | a=10.815 Z = 1 | 1265.0 | 6.023 | band gap 0.8 eV; clathrate | [4] | |
α-Arsenic telluride iodide | AsTeI | monoclinic | P21 | a=8.965 b=4.042 c=10.341 β=90.75 Z=4 | 5.84 | melt 281°C black | [5] | |
β-Arsenic telluride iodide | AsTeI | cubic | Fm3m | a=5.791 Z=2 | 5.63 | black metallic | [5] | |
As4Te5I2 | monoclinic | a=14.58 b=4.00 c=12.26 β=95.0 Z=2 | 5.51 | melt 303 °C metallic | [5] | |||
triniobium telluride heptaiodide | Nb3TeI7 | [1] | ||||||
NbTe4I | P21/c | a=7.695 b=15.393 c=13.438 β=100.84 Z=8 | 1563.2 | 6.205 | black metallic | [6] | ||
diniobium hexatelluride iodide | Nb2Te6I | P21/c | a=9.197 b=13.387 c=9.651 β=112.36 | 1093.8 | 6.548 | [1][7] | ||
Nb4Te12I | monoclinic | C12/c1 | a=21.957 b=6.147 c=19.925 β=122.40 Z=4 | 2270.6 | 5.8 | black | [8] | |
Nb4Te17I4 | monoclinic | C2/c | a = 16.199 b = 8.128 c = 27.355 β = 110.84°, Z = 4 | black metallic | [9] | |||
Mo3Tel0Il0 | [1] | |||||||
[Mo3Se7(TeI3)I2]I | monoclinic | P23/n | a=10.4969 b=13.029 c=16.567 β =102.921° Z=4 | 2208.3 | 5.202 | [1][10] | ||
[Mo3Te7(TeI3)3]2(I)(TeI3) | triclinic | P1 | a=11.2148 b=11.6550 c=16.6798 α=92.124 β=102.223 γ=117.427 Z= | 1868.4 | 5.374 | [1][10] | ||
Palladium telluride iodide | PdTeI | a=7.821 c=5.659 | brass yellow | [11][12] | ||||
Ag23Te12I | orthorhombic | Pnnm | honeycomb Te | [1] | ||||
Ag19Te6Br5.4I1.6 | orthorhombic | Pnma | electric conductor | [1] | ||||
indium telluride iodide | InTeI | monoclinic | P21/c | [13] | ||||
Antimony telluride iodide | SbTeI | triclinic | P1 | [1] | ||||
(Sb2Te2)I[AlI4] | monoclinic | P21/n | [1] | |||||
La2TeI2 | rhombohedral | R3m | a = 4.5074 c = 32.528 Z = 3 | metallic | [1][14] | |||
Er17.3Te24I8 | Fd3m | a=12.020 | [15] | |||||
Ta3TeI7 | hexagonal | P63mc | [1] | |||||
[TaTe4]4[PtI6]I2 | triclinic | P1 | a=16.831 b=17.740 c=19.018 α=93.57 β=94.08 γ=102.09 Z=1 | 977.65 | [16] | |||
TaTe4I | triclinic | P1 | a=6.679 b=7.787 c=8.581 α=112.76 β=102.60 γ=101.25 Z=2 | 381.8 | 7.118 | black | [6] | |
W2Cl12Te6I2 | [17] | |||||||
Gold telluride iodide | AuITe | monoclinic | a=7.317 b=7.626 c=7.249 β=106.33 | 7.73 | semiconductor band gap 0.9 grey melt 360°C | [18] | ||
Gold telluride diiodide | AuITe2 | orthorhombic | Pmmb | a = 4.056 Å, b = 12.579 Å, c = 4.741 Å, Z = 2 | 241.9 | 7.989 | silvery white conductor melt 440°C | [19] |
Hg3Te2I2 | greyish red | [1] | ||||||
Hg3Te2BrI | monoclinic | C2 | 18.376 b=9.587 c=10.575 β=100.11° | [20] | ||||
Hg3TeI4 | cubic | F43m | a=6.244 Z=(80% partial occupancy) | 243.4 | 7.03 | decompose 273°C dark ruby red | [21] | |
Bismuth telluride iodide | BiTeI | P3m1 / Pnma | over 3.9 GPa Weyl semimetal; under semimetal | [1] | ||||
ThTe2I2 | monoclinic | C2/m | a = 7.642 b = 14.336 c = 7.727 and β = 111.27° Z = 4 | [22] | ||||
[Ta7(Se2)14][U2I10]2 | orthorhombic | Cccm | a = 21.5134 b = 22.1619 and c = 16.7834 Z=4 | [23] | ||||
References
- 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews. 347: 23–47. doi:10.1016/j.ccr.2017.06.010.
- ↑ Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride". Journal of Solid State Chemistry. 18 (2): 183–189. Bibcode:1976JSSCh..18..183C. doi:10.1016/0022-4596(76)90094-3.
- ↑ Fenner, J.; Rabenau, A. (September 1976). "Über Tellurhalogenide des Kupfers mit hoher Ionen-Teilleitfähigkeit Die Kristallstruktur von CuTeJ" [Telluride halides of copper with high ionic partial conductivity]. Zeitschrift für anorganische und allgemeine Chemie (in German). 426 (1): 7–14. doi:10.1002/zaac.19764260103. ISSN 0044-2313.
- ↑ Kovnir, Kirill A.; Abramchuk, Nikolay S.; Zaikina, Julia V.; Baitinger, Michael; Burkhardt, Ulrich; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Dikarev, Evgeny V.; Shevelkov, Andrei V. (2006-05-01). "Ge 40.0 Te 5.3 I 8 : synthesis, crystal structure, and properties of a new clathrate-I compound". Zeitschrift für Kristallographie - Crystalline Materials. 221 (5–7): 527–532. Bibcode:2006ZK....221..527K. doi:10.1524/zkri.2006.221.5-7.527. ISSN 2196-7105. S2CID 59375600.
- 1 2 3 Kniep, Rüdiger; Reski, Horst Dieter (February 1981). "Chalcogenide Iodides of Arsenic". Angewandte Chemie International Edition in English. 20 (2): 212–214. doi:10.1002/anie.198102121. ISSN 0570-0833.
- 1 2 Tremel, Wolfgang (October 1992). "NbTe4I und TaTe4I, zwei neue Tellurid-Iodide mit Kettenstruktur". Chemische Berichte (in German). 125 (10): 2165–2170. doi:10.1002/cber.19921251002.
- ↑ Tremel, Wolfgang (March 1992). "Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group". Inorganic Chemistry. 31 (5): 755–760. doi:10.1021/ic00031a012. ISSN 0020-1669.
- ↑ Deng, S.; Zhuang, H.; Lu, C.; Huang, Jinshun; Huang, Jingling (1993-06-15). "A new type of one-dimensional compound: structure of Nb4(Te2)4Te4I". Acta Crystallographica Section C Crystal Structure Communications. 49 (6): 1135–1137. Bibcode:1993AcCrC..49.1135D. doi:10.1107/S010827019201285X.
- ↑ Tremel, Wolfgang (January 1994). "Nb4Te17I4, a New Pseudo One-Dimensional Solid-State Polytelluride". Chemische Berichte (in German). 127 (1): 11–14. doi:10.1002/cber.19941270103.
- 1 2 Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †". Inorganic Chemistry. 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541.
- ↑ Güler-Kılıç, Sümeyra; Kılıç, Çetin (2015-06-08). "Crystal and electronic structure of BiTeI, AuTeI, and PdTeI compounds: A dispersion-corrected density-functional study". Physical Review B. 91 (24): 245204. arXiv:1506.05687. Bibcode:2015PhRvB..91x5204G. doi:10.1103/PhysRevB.91.245204. ISSN 1098-0121. S2CID 118467913.
- ↑ Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal". Angewandte Chemie International Edition in English. 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833.
- ↑ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials. 18 (10): 2538–2544. doi:10.1021/cm060226m.
- ↑ Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (December 2006). "La 2 TeI 2 : A New Layered Telluride Iodide with Unusual Electrical Properties". Inorganic Chemistry. 45 (26): 10728–10733. doi:10.1021/ic061675r. ISSN 0020-1669. PMID 17173429.
- ↑ Stöwe, K (August 1998). "Nonstoichiometry in Er–Te Binary and Er–Te–I Ternary Systems". Journal of Solid State Chemistry. 139 (1): 57–65. doi:10.1006/jssc.1998.7807.
- ↑ Tremel, Wolfgang; Stork, Karl-Ludwig (1993-09-01). "[TaTe4]4[PtI6]I2, ein neues quaternäres Tellurid-Iodid mit Kettenstruktur / [TaTe4]4[PtI6]I2, A New Quaternary Telluride-Iodide with Chain Structure". Zeitschrift für Naturforschung B. 48 (9): 1155–1160. doi:10.1515/znb-1993-0901. ISSN 1865-7117. S2CID 93309355.
- ↑ Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides". Angewandte Chemie International Edition in English. 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
- ↑ Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold". Journal of the Less Common Metals. 21 (4): 395–401. doi:10.1016/0022-5088(70)90043-3.
- ↑ Haendler, H.M.; Mootz, D.; Rabenau, A.; Rosenstein, G. (June 1974). "The crystal structures of AuTe2Cl and AuTe2I". Journal of Solid State Chemistry. 10 (2): 175–181. Bibcode:1974JSSCh..10..175H. doi:10.1016/0022-4596(74)90024-3.
- ↑ Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2". Journal of Alloys and Compounds. 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020.
- ↑ Wiedemeier, Heribert; Hutchins, Mark A.; Grin, Yuri; Feldmann, Claus; von Schnering, Hans Georg (November 1997). "The Synthesis and Crystal Structure of Hg3TeI4". Zeitschrift für anorganische und allgemeine Chemie. 623 (11): 1843–1846. doi:10.1002/zaac.19976231129. ISSN 0044-2313.
- ↑ Rocker, Frank; Tremel, Wolfgang (2001). "Synthesis and Structure of ThTe2I2". Zeitschrift für anorganische und allgemeine Chemie. 627 (6): 1305–1308. doi:10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J. ISSN 1521-3749.
- ↑ Wells, Daniel M.; Ibers, James A. (March 2010). "The [U 2 I 10 ] 2- Anion: Synthesis and Structure of [Ta 7 (Se 2 ) 14 ][U 2 I 10 ] 2". Zeitschrift für anorganische und allgemeine Chemie. 636 (3–4): 440–442. doi:10.1002/zaac.200900416.
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