Manganese monosilicide

MnSi prepared by zone melting

Structures of left-handed and right-handed MnSi crystals (3 presentations, with different numbers of atoms per unit cell)
Names
IUPAC name
Manganese silicide
Identifiers
3D model (JSmol)
  • InChI=1S/Mn.Si
    Key: PYLLWONICXJARP-UHFFFAOYSA-N
  • [Si].[Mn]
Properties
MnSi
Molar mass 83.023 g/mol
Melting point 1,280 °C (2,340 °F; 1,550 K)[1]
31.3×10−6 emu/g[2]
Thermal conductivity 0.1 W/(cm·K)[1]
Structure
Cubic[3]
P213 (No. 198), cP8
a = 0.45598(2) nm
4
Hazards
Flash point Non-flammable
Related compounds
Other anions
 Manganese germanide
Other cations
 Iron silicide
Cobalt silicide
Related compounds
 Manganese disilicide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Manganese monosilicide (MnSi) is an intermetallic compound, a silicide of manganese. It occurs in cosmic dust as the mineral brownleeite. MnSi has a cubic crystal lattice with no inversion center; therefore its crystal structure is helical, with right-hand and left-hand chiralities.

MnSi is a paramagnetic metal that turns into a ferromagnet at cryogenic temperatures below 29 K. In the ferromagnetic state, the spatial arrangement of electron spins in MnSi changes with magnetic field, forming helical, conical, skyrmion, and regular ferromagnetic phases.

Crystal structure and magnetism

Magnetic phase diagram of MnSi. At low temperatures, with increasing magnetic field, spins in MnSi form helical, conical, skyrmion (SkS) and regular ferromagnetic spatial structures. At high temperatures the spin orientation is random (paramagnetic)
Simulated and measured (by STXM) images of helical, skyrmion and conical phases in FeGe. All magnetic properties are very similar in FeGe and MnSi, except for Tc values.

Manganese monosilicide is a non-stoichiometric compound, meaning that the 1:1 Mn:Si composition, lattice constant and many other properties vary depending on the synthesis and processing history of the crystal.[3]

MnSi has a cubic crystal lattice with no inversion center; therefore its crystal structure is helical, with right-hand and left-hand chiralities. At low temperatures and magnetic fields, the magnetic structure of MnSi can be described as a stack of ferromagnetically ordered layers lying parallel to the (111) crystallographic planes. The direction of magnetic moment varies from layer to layer by a small angle due to the antisymmetric exchange.[3]

Upon cooling to temperatures below Tc = 29 K, MnSi changes from a paramagnetic into a ferromagnetic state; the transition temperature Tc decreases with increasing pressure, vanishing at 1.4 GPa.[3]

Electron spins in MnSi show dissimilar, yet regular spatial arrangements at different values of applied magnetic field. Those arrangements are named helical, skyrmion, conical, and regular ferromagnetic. They can be controlled not only by temperature and magnetic field, but also by electric current, and the current density required for manipulating skyrmions (~106 A/m2) is approximately one million times smaller than that needed for moving magnetic domains in traditional ferromagnets. As a result, skyrmions in MnSi have potential application in ultrahigh-density magnetic storage devices.[4]

Synthesis

Centimeter-scale single crystals of MnSi can be prepared by direct crystallization from the melt using the Bridgman, zone melting or Czochralski methods.[3]

References

Wikimedia Commons has media related to Manganese silicide.
  1. 1 2 Levinson, Lionel M. (1973). "Investigation of the defect manganese silicide MnnSi2n−m". Journal of Solid State Chemistry. 6 (1): 126–135. Bibcode:1973JSSCh...6..126L. doi:10.1016/0022-4596(73)90212-0.
  2. ↑ Shinoda, Daizaburo; Asanabe, Sizuo (1966). "Magnetic Properties of Silicides of Iron Group Transition Elements". Journal of the Physical Society of Japan. 21 (3): 555. Bibcode:1966JPSJ...21..555S. doi:10.1143/JPSJ.21.555.
  3. 1 2 3 4 5 Stishov, Sergei M.; Petrova, Alla E. (2011). "Itinerant helimagnetic compound MnSi". Uspekhi Fizicheskikh Nauk. 181 (11): 1157. doi:10.3367/UFNr.0181.201111b.1157.
  4. ↑ Nagaosa, Naoto; Tokura, Yoshinori (2013). "Topological properties and dynamics of magnetic skyrmions". Nature Nanotechnology. 8 (12): 899–911. Bibcode:2013NatNa...8..899N. doi:10.1038/nnano.2013.243. PMID 24302027.
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