Ottavio is the Italian form of Octavius. Its feminine given name version is Ottavia. Ottavio may refer to:
Given name
- Ottavio Cinquanta, the President of the International Skating Union
- Ottavio Leoni, Italian painter
- Ottavio Piccolomini, (1599–1656), Italian nobleman and general
- Ottavio Rinuccini (1562–1621), Italian composer
- Ottavio Serena (1837–1914), Italian politician and judge
Middle name
- Giuseppe Ottavio Pitoni (1657–1734), Italian composer
Fictional characters
- Don Ottavio, a character in Mozart's opera Don Giovanni
- One of the male innamorati of the commedia
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