The transposed Paternò−Büchi reaction involves a ππ* excited state of alkene reacting with a ground state carbonyl functionality. This is reversal of the traditional Paternò−Büchi reaction where an excited carbonyl group reacts with a ground state alkene. This strategy was first reported by Sivaguru and co-workers with reaction of enamides.[1]

References

  1. ↑ Kumarasamy, Elango; Raghunathan, Ramya; Kandappa, Sunil Kumar; Sreenithya, A.; Jockusch, Steffen; Sunoj, Raghavan B; Sivaguru, J. (2017-01-18). "Transposed Paternò–Büchi Reaction". Journal of the American Chemical Society. 139 (2): 655–662. doi:10.1021/jacs.6b05936. ISSN 0002-7863. PMID 27958726.
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