氟硼酸镍

氟硼酸镍
识别
CAS号	14708-14-6（无水） ; 14322-78-2（六水，配位水） ; 15684-36-3（六水，结晶水）
性质
化学式	Ni(BF4)2
熔点	64 °C（六水）[1]
沸点	205 °C（六水，分解）[2]
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氟硼酸镍是一种无机化合物，化学式为Ni(BF₄)₂，可由碱式碳酸镍和氟硼酸反应制得。[3]它的六水合物在120 °C长时间加热，会缓慢分解，[1]这源自于Ni²⁺催化BF₄⁻水解为BF₃OH⁻和HF。[4]它和4-氨基-1,2,4-三氮唑（NH₂trz）反应，可以得到蓝色的[Ni₃(NH₂trz)₆(H₂O)₆](BF₄)₆·4H₂O。[5]它和[PPN]₃[Os(CN)₆]反应，可以得到红橙色的Ni₃[Os(CN)₆]₂·4.04H₂O。[6]

参考文献

Plakhotnik, V. N.; Varekh, V. V. Properties and solubility polytherm of nickel(II) tetrafluoroborate hexahydrate. Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya, 1973. 16 (11): 1619-1622. ISSN 0579-2991.
Ostrovskaya, T. V.; Amirova, S. A.; Startseva, N. V. Chemical transformations of iron, cobalt, and nickel tetrafluoroborates. Zhurnal Neorganicheskoi Khimii, 1967. 12 (9): 2327-2330. ISSN 0044-457X.
Morgunova, E. M.; Strezhnev, I. V.; Pinaevskaya, E. N.; Neganova, L. A.. Development of preparation technology for some fluoroborates. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1970. 43 (5): 969-974. ISSN 0044-4618.
Plakhotnik, V. N.; Varekh, V. V. Hydrolysis of nickel tetrafluoroborate. Zhurnal Fizicheskoi Khimii, 1972. 46 (12): 3126-3129. ISSN 0044-4537.
Irene Bräunlich, Michael Medvedev, Julia Dshemuchadse, Michael Wörle, Walter Caseri. . Zeitschrift für anorganische und allgemeine Chemie. 2015-10, 641 (12-13): 2344–2349 [2022-06-22]. doi:10.1002/zaac.201500234. （原始内容存档于2022-06-22）（英语）.
Matthew G. Hilfiger, Michael Shatruk, Andrey Prosvirin, Kim R. Dunbar. . Chemical Communications. 2008, (44): 5752 [2022-06-22]. ISSN 1359-7345. doi:10.1039/b813413h （英语）.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.

[Plakhotnik-1] Plakhotnik, V. N.; Varekh, V. V. Properties and solubility polytherm of nickel(II) tetrafluoroborate hexahydrate. Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya, 1973. 16 (11): 1619-1622. ISSN 0579-2991.

[2] Ostrovskaya, T. V.; Amirova, S. A.; Startseva, N. V. Chemical transformations of iron, cobalt, and nickel tetrafluoroborates. Zhurnal Neorganicheskoi Khimii, 1967. 12 (9): 2327-2330. ISSN 0044-457X.

[3] Morgunova, E. M.; Strezhnev, I. V.; Pinaevskaya, E. N.; Neganova, L. A.. Development of preparation technology for some fluoroborates. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1970. 43 (5): 969-974. ISSN 0044-4618.

[4] Plakhotnik, V. N.; Varekh, V. V. Hydrolysis of nickel tetrafluoroborate. Zhurnal Fizicheskoi Khimii, 1972. 46 (12): 3126-3129. ISSN 0044-4537.

[5] Irene Bräunlich, Michael Medvedev, Julia Dshemuchadse, Michael Wörle, Walter Caseri. . Zeitschrift für anorganische und allgemeine Chemie. 2015-10, 641 (12-13): 2344–2349 [2022-06-22]. doi:10.1002/zaac.201500234. （原始内容存档于2022-06-22）（英语）.

[6] Matthew G. Hilfiger, Michael Shatruk, Andrey Prosvirin, Kim R. Dunbar. . Chemical Communications. 2008, (44): 5752 [2022-06-22]. ISSN 1359-7345. doi:10.1039/b813413h （英语）.