硫代钼酸盐
制备
硫代钼酸盐可由相应的钼酸盐和硫化氢反应得到,反应过程中,氧原子逐步被硫取代,直至生成MoS2−
4。
曾经有过通过四硫代钼酸铵和相应的金属盐反应,试图得到钴、镍、铜、锌的四硫代钼酸盐,但都失败了,粉末XRD表征产物为相应金属的硫化物以及三硫化钼。[1]
参考文献
- G.M. Clark, W.P. Doyle. Properties of some solid tetrathiomolybdates. Journal of Inorganic and Nuclear Chemistry, 1966. 28(2): 381-385. doi:10.1016/0022-1902(66)80315-9
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