草酸钇

草酸钪是钇的草酸盐,化学式为Y2(C2O4)3。其三水合物可由氯化钇草酸反应制得。[1]氯化钇与碱金属(或铵)的草酸盐的反应则根据反应物的化学计量比生成十水合物(Y2(C2O4)3·10H2O)或复盐M[Y(C2O4)2]·nH2O。[2]草酸钇高温分解,生成氧化钇[1]

草酸钇
识别
CAS号 867-68-5  checkY
SMILES
 
  • [Y+3].[Y+3].[O-]C(=O)C(=O)[O-].[O-]C(=O)C(=O)[O-].[O-]C(=O)C(=O)[O-]
性质
化学式 Y2(C2O4)3
外观 无色晶体
溶解性 难溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. Sung, Min-Hyun; Kim, Woo-Sik; Kim, Jun-Soo. Thermal decomposition and crystal structure of yttrium oxalate produced by reaction crystallization(). Hwahak Konghak, 1998. 36 (4): 510-516. ISSN: 0304-128X.
  2. Davitashvili, E. G.; Modebadze, M. E.; Sheliya, N. G. Reaction of yttrium chloride with Na, ammonium, and K oxalates(俄文). Soobsch. Akad. Nauk Gruz. SSR, 1965. 40 (2): 325-332.
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