Bodroux–Chichibabin醛合成

波尔多-齐齐巴宾醛合成（Bodroux-Chichibabin aldehyde synthesis）[1][2][3][4][5]

格氏试剂与原甲酸三乙酯反应生成缩醛，缩醛经过水解得到比格氏试剂多一个碳的醛类。

Bodroux-Chichibabin醛合成

例如，以正戊基格氏试剂为原料合成己醛：[6]

Bodroux-Chichibabin法合成庚醛

参见

参考资料
  1. Bodroux, F. Compt. Rend. 1904, 138: 92. 缺少或|title=为空 (帮助)
  2. Tschitschibabin, A. E. . Ber. 1904, 37: 186. doi:10.1002/cber.19040370133.
  3. Tschitschibabin, A. E. . Ber. 1904, 37: 850. doi:10.1002/cber.190403701140.
  4. Smith, L. I.; Bayliss, M. . J. Org. Chem. 1941, 6: 437. doi:10.1021/jo01203a009.
  5. Smith, L. I.; Nichols, J. . J. Org. Chem. 1941, 6: 489. doi:10.1021/jo01204a003.
  6. G. Bryant Bachman (1943). "n-Hexaldehyde". Org. Synth.; Coll. Vol. 2: 323.
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