Aza Paternò−Büchi reaction involves an ππ* excited state of alkene reacting with a ground state imine. This strategy was developed by the laboratory Sivaguru and co-workers[1] to overcome the shortcomings involving direct excitation of imines. Traditionally addition of excited imines to carbon-carbon double bonds involves making the imines as part of a carbocycle.[2]

References

  1. ↑ Kumarasamy, Elango; Kandappa, Sunil Kumar; Raghunathan, Ramya; Jockusch, Steffen; Sivaguru, Jayaraman (2017-06-12). "Realizing an Aza Paternò-Büchi Reaction". Angewandte Chemie International Edition. 56 (25): 7056–7061. doi:10.1002/anie.201702273. PMID 28452104.
  2. ↑ Padwa, Albert. (February 1977). "Photochemistry of the carbon-nitrogen double bond". Chemical Reviews. 77 (1): 37–68. doi:10.1021/cr60305a004. ISSN 0009-2665.
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