Baccharis oxide synthase
Identifiers
EC no.5.4.99.51
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
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PMCarticles
PubMedarticles
NCBIproteins

Baccharis oxide synthase (EC 5.4.99.51) is an enzyme with systematic name (3S)-2,3-epoxy-2,3-dihydrosqualene mutase (cyclizing, baccharis-oxide-forming).[1] This enzyme catalyses the following chemical reaction

(3S)-2,3-epoxy-2,3-dihydrosqualene baccharis oxide

The enzyme from Stevia rebaudiana also gives traces of other triterpenoids.

References

  1. Shibuya M, Sagara A, Saitoh A, Kushiro T, Ebizuka Y (November 2008). "Biosynthesis of baccharis oxide, a triterpene with a 3,10-oxide bridge in the A-ring". Organic Letters. 10 (21): 5071–4. doi:10.1021/ol802072y. PMID 18850716.
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