Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

List

formula system space group unit cell Å volume density comment ref
(Ca2−x□x)(As1−xBr1+x) Ca2AsBr cubic a=6.05 3.47 yellow, or dark brown [1][2]
Ca3AsBr3 cubic Pm3 a=5.91 3.48 colourless or yellow [1][2]
Cu6AsS5Br cubic F43m a=9.8763 4.80 [3][4]
(Ge38As8)+8⋅8 I− cubic Pm3n a=10.625 5.71 semiconductor resistivity 1 Ω cm; band gap 0.9 eV; silvery grey [5]
I8As21Ge25 cubic Pm3n a=10.5963 Z=1 1189.77 6.143 colourless [6]
Cd2As3Br monoclinic C2/c a = 8.281, b = 9.411, c = 7.993, β = 101.49°, z = 4 5.76 black [7][8]
Cd4As2Br3 cubic Pa3 a=12.61 5.51 semiconductor band gap 1.8 eV [9]
Cd4PAsBr3 cubic Pa3 a=12.521 5.38 [10][4]
Cd4As2I1.5Br1.5 cubic Pa3 a=12.83 [11][4]
La3AsBr3 cubic I4132 a=12.09 5.50 [12]
Pr3AsBr3 cubic I4132 a=12.02 5.64 [12]
Hg2As3Br monoclinic C2/c a = 8.0914, b = 9.300, c = 8.1084, β = 99.323°, z = 4 7.79 black [7]
Hg4As2Br3 cubic Pa3 a=12.610 Z=8 2012.4 5.54 7.90 red; dark grey [13][14]
Hg19As10Br18 triclinic P1 a = 11.262, b = 11.352, c = 12.309, α = 105.724, β = 105.788, γ = 109.078° 1314.3 dark brown [15]
(HgBr2)3(As4S4)2 monoclinic P21/c a = 9.593, b = 11.395, c = 13.402, β = 107.27, Z = 2 1399 [16]
Hg3AsS4Br hexagonal P63mc a = 7.430, c = 9.364 Z=2 [17]
(Hg6As4)[TiBr6]Br cubic Pa3 a= 1230.9 [18]
[Hg6As4](CrBr6)Br cubic Pa a=12.275 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](FeBr6)Hg0.6 cubic Pa a=12.332 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](CuBr3)2 monoclinic I2/a a = 14.884, b = 9.358, c = 20.413, β=92.88°, Z = 6 dark red [20]
[Hg11As4](GaBr4)4 monoclinic C2/m [21]
Hg3AsSe4Br hexagonal P63mc a = 7.707, c = 9.47 Z=2 [17]
(Hg2Cd2As2Br)Br orthorhombic Pmma a = 8.791, b = 4.701, c = 9.779, Z=2 404.2 7.688 dark red [22]
(Hg6As4)(CdBr6) cubic Pa3 a=12.3738 Z=4 1894.6 7.345 red; air stable; band gap 1.94 [23]
[Hg6As4][InBr6]Br cubic Pa3 a=12.3511 Z=4 1884.2 dark red [24]
[Hg4As2](InBr3.5As0.5) Hexagonal P63/mmc a = 7.7408, c = 12.535, Z=2 650.47 [25]
[Hg6As4Br3](SnBr3) cubic P213 a=12.383 Z=4 [26]
[Hg6As4][YbBr6]Br cubic Pa3 a=12.362 Z=4 1889.1 7.860 dark red [27]
Hg9As4Bi2Br12 tetragonal P43 a=10.865 b=10.865 c=28.357 Z=4 3347.5 6.91 orange [28]

References

  1. 1 2 Hadenfeldt, C.; Schulz, P. (November 1984). "Darstellung, Struktur und Temperaturabhängigkeit der Phasenbreite der Phase Ca2-xAs1-xBr1+x und thermisches Verhalten der Verbindung Ca3AsBr3". Zeitschrift für anorganische und allgemeine Chemie (in German). 518 (11): 77–86. doi:10.1002/zaac.19845181108. ISSN 0044-2313.
  2. 1 2 Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3". Zeitschrift für Naturforschung B. 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117. S2CID 95122668.
  3. ↑ Nilges, Tom; Pfitzner, Arno (2005-03-01). "A structural differentiation of quaternary copper argyrodites: Structure — property relations of high temperature ion conductors". Zeitschrift für Kristallographie - Crystalline Materials. 220 (2–3): 281–294. Bibcode:2005ZK....220..281N. doi:10.1524/zkri.220.2.281.59142. ISSN 2196-7105. S2CID 56213950.
  4. 1 2 3 Handbook of Inorganic Compounds 2015. 2015. p. 826.
  5. ↑ Chu, T. L.; Chu, Shirley S.; Ray, R. L. (October 1982). "Germanium arsenide iodide: A clathrate semiconductor". Journal of Applied Physics. 53 (10): 7102–7103. Bibcode:1982JAP....53.7102C. doi:10.1063/1.330019. ISSN 0021-8979.
  6. ↑ Ayouz, Katia; Kars, Mohammed; Rebbah, Allaoua; Rebbah, Houria (2009-03-15). "I 8 As 21 Ge 25". Acta Crystallographica Section E. 65 (3): i15. Bibcode:2009AcCrE..65I..15A. doi:10.1107/S1600536809004991. ISSN 1600-5368. PMC 2968696. PMID 21582033.
  7. 1 2 Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (November 1994). "A Novel Metallic Halide, Hg2As3Br: Synthesis and Crystal Structure, and Crystal Structure of Cd2As3Br". Journal of Solid State Chemistry. 113 (1): 116–119. Bibcode:1994JSSCh.113..116S. doi:10.1006/jssc.1994.1348.
  8. ↑ Breitinger, Dietrich; Herrmann, Wolfgang A.; Hiller, Wolfgang (2014-05-14). Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 5, 1999: Volume 5: Copper, Silver, Gold, Zinc, Cadmium and Mercury. Georg Thieme Verlag. p. 178. ISBN 978-3-13-179211-2.
  9. ↑ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe". Solid State Communications. 255–256: 5–10. Bibcode:2017SSCom.255....5R. doi:10.1016/j.ssc.2017.03.001.
  10. ↑ REBBAH, A; A, DESCHANVRES (1981). "STRUCTURE CRISTALLINE DE Cd4PAsBr3". Ann. Chim. 6 (7): 585–590.
  11. ↑ GAM, NS (1988). "PRODUCTION AND PROPERTIES OF CRYSTALS OF Cd4As2BrXI3-X SOLID-SOLUTIONS". Inorganic Materials. 24 (9): 1348–1350.
  12. 1 2 Handbook of Inorganic Substances 2015. 2015. p. 245.
  13. ↑ Shevelkov, Andrei V.; Dikarev, Evgeny V.; Popovkin, Boris A. (November 1996). "Two New Cubic Structures of Mercury Arsenidehalides". Journal of Solid State Chemistry. 126 (2): 324–327. Bibcode:1996JSSCh.126..324S. doi:10.1006/jssc.1996.0344.
  14. ↑ Kars, Mohammed; Roisnel, Thierry; Dorcet, Vincent; Rebbah, Allaoua; Otero-Diáz, L. Carlos (2014-03-01). "Cd 4 As 2 Br 3". Acta Crystallographica Section E. 70 (3): i15. Bibcode:2014AcCrE..70I..15K. doi:10.1107/S160053681400395X. ISSN 1600-5368. PMC 3998459. PMID 24764933.
  15. ↑ "Synthesis, crystal and band structures, and optical properties of mercury pnictide halide Hg19As10Br18". Chinese Journal of Structural Chemistry. 30 (12): 1827–1832. 15 December 2011.
  16. ↑ Bräu, Michael F.; Pfitzner, Arno (June 2007). "(HgBr2)3(As4S4)2: An Adduct of HgBr2 Molecules and Undistorted As4S4 Cages". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (7): 935–937. doi:10.1002/zaac.200600363.
  17. 1 2 Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.
  18. ↑ Beck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br". Zeitschrift für Anorganische und Allgemeine Chemie. 626 (7): 1620–1626. doi:10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R.
  19. 1 2 Olenev, Andrei V.; Oleneva, Olga S.; Lindsjö, Martin; Kloo, Lars A.; Shevelkov, Andrei V. (2003-07-21). "Coordinated and Clathrated Guests in the [Hg6As4]4+ Bicompartmental Framework: Synthesis, Crystal and Electronic Structure, and Properties of the Novel Supramolecular Complexes [Hg6As4](CrBr6)Br and [Hg6As4](FeBr6)Hg0.6". Chemistry - A European Journal. 9 (14): 3201–3208. doi:10.1002/chem.200204687. PMID 12866063.
  20. ↑ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005). "Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework". Journal of Cluster Science. 16 (2): 273–285. doi:10.1007/s10876-005-4548-y. ISSN 1040-7278. S2CID 95453360.
  21. ↑ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.
  22. ↑ Zou, Jian-Ping; Guo; Chen, Wen-Tong; Liu, Xi; Fu, Ming-Lai; Zhang; Huang, Jin-Shun (2006-08-01). "Synthesis, Crystal and Band Structures, and Optical Properties of a New Quaternary Metal Pnictidehalide: (Hg 2 Cd 2 As 2 Br)Br". Inorganic Chemistry. 45 (16): 6365–6369. doi:10.1021/ic060503r. ISSN 0020-1669. PMID 16878947.
  23. ↑ Zou, Jian-Ping; Li, Yan; Fu, Ming-Lai; Guo, Guo-Cong; Xu, Gang; Liu, Xue-Hui; Zhou, Wei-Wei; Huang, Jin-Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)". European Journal of Inorganic Chemistry. 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948.
  24. ↑ Deiseroth, Hans-Jörg; Schlirf, Jens; Reiner, Christof (June 2009). "Crystal structure of tetraarsenidohexamercury hexabromoindate bromide, [Hg6As4][InBr6]Br and tetraantimonidohexamercury hexabromoindate bromide, [Hg6Sb4][InBr6]Br". Zeitschrift für Kristallographie - New Crystal Structures. 224 (2): 167–168. doi:10.1524/ncrs.2009.0075. S2CID 201061929.
  25. ↑ Zou, Jian-Ping; Luo, Sheng-Lian; Tang, Xing-Hua; Li, Ming-Jun; Zhang, Ai-Qin; Peng, Qiang; Guo, Guo-Cong (January 2011). "Synthesis, crystal and band structures, and optical properties of a new framework mercury pnictides: [Hg4As2](InBr3.5As0.5) with tridymite topology". Journal of Alloys and Compounds. 509 (2): 221–225. doi:10.1016/j.jallcom.2010.09.035.
  26. ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
  27. ↑ Olenev, Andrei V.; Shestimerova, Tatiana A.; Schnelle, Walter; Shevelkov, Andrei V. (July 2005). "Synthesis, Structure, and Properties of [Hg6As4][YbBr6]Br, a Supramolecular Assembly Featuring a Discrete [YbBr6]3− Anion". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (9): 1698–1701. doi:10.1002/zaac.200500059. ISSN 0044-2313.
  28. ↑ Puff, H.; Grönke, M.; Kilger, B.; Möltgen, P. (November 1984). "Darstellung und Struktur des Mercuroarsoniumbromo-bismutats [Hg7(HgBr)2As4] [Bi2Br10]". Zeitschrift für anorganische und allgemeine Chemie (in German). 518 (11): 120–128. doi:10.1002/zaac.19845181112. ISSN 0044-2313.
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