A chloride nitride is a mixed anion compound containing both chloride (Cl−) and nitride ions (N3−). Another name is metallochloronitrides. They are a subclass of halide nitrides or pnictide halides.[1]

The group 4 element chloride nitrides can be intercalated by alkali metals that supply extra electrons, and other molecules such as from solvents like tetrahydrofuran, yielding layered substances that are superconductors. A superconductor transition temperature Tc of 25.5K has been achieved.[2]

Production

Nitride chlorides may be produced by heating metal nitrides with metal chlorides. The ammonolysis process heats a metal chloride with ammonia.[3] A related method heats a metal or metal hydride with ammonium chloride. The nitrogen source could also be an azide or an amide.[3]

List

name formula formula
weight		 crystal
system		 space
group		 unit cell Å volume density comments ref
Li4NCl hexagonal R3 a=366.225 c=1977.18 Z=3 [4]
Li1.8N0.4Cl0.6 Li ion conductor [5]
Cyanogen chloride ClCN molecular
Magnesium nitride chloride Mg2NCl hexagonal R3m a = 3.2994 c = 17.857 [6]
phosphonitrilic chloride cyclic trimer P3N3Cl6 molecular
trithiazyl trichloride S3N3Cl3 cas 5964-00-1 [7]
Ca2NCl hexagonal R3m a 3.6665 c 19.7187 [8]
Sc2Cl2N P3m1 a = 3:517 c = 8.813 layered [1]
Sc4Cl6N orthorhombic Pbam a = 11.625, b = 12.118, c = 3.5447 [1]
Sc5Cl8N C2/m a = 17.85, b = 3.5505, c = 12.090, β = 130.13 [1]
Sc7Cl12N R3 a = 12.990, c = 8.835 Sc6N clusters [1]
Titanium nitride chloride TiNCl orthorhombic Pmmn a=3.275 b=3.967 c=8.402

a = 3.937, b = 3.258, c = 7.803

 109.2 black [9]
Li0.6TiNCl [9]
Cl3VNCl triclinic P1 a = 7.64, b = 7.14, c = 5.91, α = 94.9, β = 112.4, γ = 107.8 V=NCl complex [1]
Zn2NCl 180.20 orthorhombic Pna21 a=6.137 b=7.394 c=5.940 Z=4 269.5 4.441 band gap 3.21 eV [10]
Zn2NCl orthorhombic Pnma Z=16 predicted [11]
Zn2NCl hexagonal R3m predicted [11]
Sr2BN2Cl [12]
α-Y2Cl3N orthorhombic Pbcn a = 12.761, b = 6.676, c = 6.1000 [1]
β-Y2Cl3N C2/m a = 15.248, b = 3.8520, c = 10.157, β = 118.41 [1]
α-ZrNCl orthorhombic Pmmn a = 3.937, b = 3.258, c = 7.803 pale yellow-green [1]
β-zirconium nitride chloride β-ZrNCl hexagonal R3m a = 3.6031, c = 27.672 yellow-green;semiconductor; layers of Cl–Zr–N–N–Zr–Cl [13][1]
Zr6Cl15N cubic Ia3d a = 21.171 [1]
Lithium-intercalated β-zirconium nitride chloride LixZrNCl black; superconductor Tc=12.5 K [14]
NaxZrNCl superconductor Tc 15 K [13]
KxZrNCl superconductor Tc 15 K [13]
molybdenum nitride chloride MoNCl3 triclinic P1 a = 9.14, b = 7.67, c = 8.15, α = 108.8, β = 99.3, γ= 108.6 [15][1]
Mo2NCl7 triclinic P1 a = 9.057, b = 9.754, c = 12.834, α = 103.13, β = 109.83, γ = 98.58 [1]
Mo2NCl8 monoclinic P2/c a = 9.961, b = 6.294, c = 17.808, β = 101.82 [1]
Phenyldiazonium tetrachloronitridomolybdate C6H5N2[MoNCl4] monoclinic P21/c a = 12.83, b = 11.70, c = 19.22 β = 94.11 Z=2 dark red [15]
Technetium chloride nitride TcCl3N black; cas 154525-32-3 [7]
(Ph4As)[TcNCl4] [16]
[Se3N2Cl]+SbCl6- triclinic P1 a=6.982 b=6.997 c=15.105 α = 89.45°, β = 86.18°, γ = 68.22° Z=2 red [17]
Ba2NCl hexagonal R3m
Ba3Si3N5OCl P62c a=9.560 c=5.552 [18]
Ba25Nb5N19Cl18 [1]
LiBa4[Mo2N7]BaCl2 [1]
La2NCl3 orthorhombic Ibam a = 13.758, b = 6.922, c = 6.185 [19]
La2Cl(CN2)N orthorhombic Cmmm a = 13.340, b = 9.5267, c = 3.9402, Z=4 [20]
La6N3S4Cl orthorhombic Pnma a = 11.597; b = 4.1095; c = 27.568 Z=4 [21]
CeNCl tetragonal P4/nmm a=4.079 c=6.837 Z= black [22]
Cerium(III) nitride chloride Ce2NCl3 orthorhombic Ibam a = 13.6021 b=6.8903 c= 6.1396 Z=4 575.42 4.624 Light yellow [23]
Ce2Cl(CN2)N orthorhombic Cmmm a = 13.3914, b = 9.6345, c = 3.9568, Z=4 [20]
Ce6Cl12N2 1294.1 monoclinic P21/c a=11.233 b=16.527 c=10.798 β =90.15 Z=4 1988 4.324 yellow [22]
Na2[{(ON)Ce4}Cl9] monoclinic P21/m a = 8.1321, b = 11.4613, c = 9.4286 and β = 107.504° Z=2 [24]
Pr2NCl3 orthorhombic Ibam a = 13.531, b = 6.8512, c = 6.1072 [19]
Pr5N3S2Cl2 monoclinic C2/m a = 15.402; b = 4.0092; c = 16.563; β = 101.24°, Z = 4 [25]
Pr6N3S4Cl orthorhombic Pnma a=11.3987 b=4.0235 c=26.999 Z=4 1238.3 reddish-brown [26]
Nd2NCl3 orthorhombic Pbcn a = 13.382, b = 6.8462, c = 6.1815 [19]
Nd3NCl6 orthorhombic Pbca a = 10.4971, b = 11.0683, c = 16.211; Z = 8 [27]
Nd4NS3Cl3 hexagonal P63mc a = 9.2278, c = 6.8306; Z = 2 [27]
Nd6N3S4Cl orthorhombic Pnma a = 11.371; b = 3.9934; c = 26.876 [21]
Na2Nd4ONCl9 monoclinic P21/m a = 8.0354, b = 11.3426, c = 9.2831 and β = 107.109° [28]
Trigadolinium hexachloride nitride Gd3Cl6N 698.485 triclinic P1 a = 7.107, b = 8.156, c = 9.707, α = 75.37°, β = 109.10°, γ = 114.64° Z=2 478.8 4.84 colourless; water sensitive; biaxial (−) [29]
Gd2NCl3 orthorhombic Pbcn a=13.017 b=6.7310 c=6.1403 [19]
Gd2N2Cl tetragonal P4mm a = 4.25 c = 5.92 [30]
α-HfNCl orthorhombic Pmmn a = 4.130, b = 3.497, c = 8.070 [31][1]
β-HfNCl hexagonal R3m a = 3.5744, c = 27.7075 colourless [1]
NaxHfNCl superconductor Tc 25 K [32]
Ba3Ta3N6Cl P62c a =10.1455 c =5.9770 [18]
Ba3Cl2TaN3 hexagonal P63cm a = 15.0739, c = 6.3298; Z = 6 light yellow [33]
Ba15Ta15N33Cl4 P62c a =10.1545 c =29.917 [18]
W2NCl8 triclinic P1 a = 6.2423, b = 6.309, c = 6.931, α = 89.76, β = 81.51, γ = 82.68 [1]
W2NCl9 P21/c a = 8.421, b = 16.786, c = 11.930, β = 134.74° [1]
[WNCl3 • POCl3]4 • 2 POCl3 triclinic P1 a = 12.257 b = 11.851 c = 19.27.0 α = 102.6° β= 108.4° γ = 94.8° Z=2 [34]
Ba4[WN4]Cl2 [1]
ReNCl4 tetragonal I4 a=8.278 b=8.281 c=4.057 Z=2 brown [35][36]
ReNCl4·H2O orthorhombic Pnma a = 10.754, b = 11.085, c = 547.7 Z=4 red [36]
[NBu4][ReNCl4] orthorhombic P4/n a 11.795 b 11.795 c 8.466 ReN triple bond in complex [37]
K2OsNCl5 orthorhombic Pnma a = 13.27, b = 9.85, c = 6.84 [1]
Kleinite Hg2N(Cl,SO4)•n(H2O) hexagonal C63/mmc a = 13.56 c = 11.13 Z = 18 1,772.33 8.01 yellow [38]
Mosesite Hg2N(Cl,SO4,MoO4,CO3)•(H2O) cubic F43m a = 9.524, Z = 8 863.89 7.71 yellow; refractive index 2.065 [39]
ThNCl tetragonal P4/nmm a =4.09486 c =6.9013 [40]
Uranium nitride chloride UNCl tetragonal P4/nmm a=3.97 c=6.81 Z=2 [41]

References

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  2. ↑ Yamanaka, Shoji (2010). "Intercalation and superconductivity in ternary layer structured metal nitride halides (MNX: M = Ti, Zr, Hf; X = Cl, Br, I)". Journal of Materials Chemistry. 20 (15): 2922. doi:10.1039/b922149b. ISSN 0959-9428.
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  4. ↑ Marx, Rupert (February 1997). "Preparation and Crystal Structure of Lithium Nitride Chloride Li4NCl". Journal of Solid State Chemistry. 128 (2): 241–246. Bibcode:1997JSSCh.128..241M. doi:10.1006/jssc.1996.7196.
  5. ↑ Hartwig, P.; Weppner, W.; Wichelhaus, W. (April 1979). "Fast ionic lithium conduction in solid lithium nitride chloride". Materials Research Bulletin. 14 (4): 493–498. doi:10.1016/0025-5408(79)90191-0.
  6. ↑ Li, Yanqing; George, Janine; Liu, Xiaohui; Dronskowski, Richard (February 2015). "Synthesis, Structure Determination and Electronic Structure of Magnesium Nitride Chloride, Mg 2 NCl: Magnesium Nitride Chloride, Mg 2 NCl". Zeitschrift für anorganische und allgemeine Chemie. 641 (2): 266–269. doi:10.1002/zaac.201400496.
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  12. ↑ Wang, Haoyang; Li, Zebin; Kang, Runtian; Ji, Ruijie; Wang, Yuhua (2022-11-14). "Sr 2 BN 2 Cl:Eu 2+ -Based Narrow-Band Blue-Emitting Phosphor: A Potential Color Converter for Illumination and Displays". Inorganic Chemistry. 61 (45): 18245–18252. doi:10.1021/acs.inorgchem.2c03069. ISSN 0020-1669. PMID 36373304. S2CID 253309150.
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  27. 1 2 Meyer, Monika; Lissner, Falk; Schleid, Thomas (2000). "Nd3NCl6 und Nd4NS3Cl3: Zwei Neodymnitrid-Derivate mit diskreten Einheiten kantenverknüpfter ([N2Nd6]12+) bzw. isolierter [NNd4]9+-Tetraeder". Zeitschrift für anorganische und allgemeine Chemie (in German). 626 (5): 1205–1210. doi:10.1002/(SICI)1521-3749(200005)626:5<1205::AID-ZAAC1205>3.0.CO;2-T. ISSN 1521-3749.
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  29. ↑ Simon, A.; Koehler, T. (February 1986). "A new gadolinium nitride chloride—Gd3Cl6N". Journal of the Less Common Metals. 116 (1): 279–292. doi:10.1016/0022-5088(86)90236-5.
  30. ↑ Chen, Ning; Liu, Xiuxia; Liu, Yang; Li, Yang (March 2013). "Study on novel rare-earth nitride chlorides GdNCl and Gd2N2Cl". APS March Meeting Abstracts. 2013: Q1.299. Bibcode:2013APS..MAR.Q1299C.
  31. ↑ Felser, Claudia; Seshadri, Ram (1999). "Electronic structures and instabilities of ZrNCl and HfNCl: implications for superconductivity in the doped compounds". Journal of Materials Chemistry. 9 (2): 459–464. doi:10.1039/a808127a.
  32. ↑ Weht, R.; Filippetti, A.; Pickett, W. E. (1999-11-01). "Electron doping in the honeycomb bilayer superconductors (Zr, Hf)NCl". EPL (Europhysics Letters). 48 (3): 320. Bibcode:1999EL.....48..320W. doi:10.1209/epl/i1999-00484-4. ISSN 0295-5075. S2CID 250844908.
  33. ↑ Blaschkowski, Björn; Dürr, Oliver; Reckeweg, Olaf; Schleid, Thomas (July 2015). "Crystal Growth and Structure of the Barium Chloride Nitridotantalate(V) Ba 3 Cl 2 TaN 3". Zeitschrift für anorganische und allgemeine Chemie. 641 (8–9): 1515–1520. doi:10.1002/zaac.201500201.
  34. ↑ Musterle, Wilfried; Strähle, Joachim; Liebelt, Wolfgang; Dehnicke, Kurt (1979-07-01). "Darstellung, IR-Spektrum und Kristallstruktur von [WNCI 3 P0Cl 3 ] 4 2 POCI 3 / Preparation, IR Spectra and Crystal Structure of [WNCl 3 • P0Cl 3 ] 4 • 2 P0Cl 3". Zeitschrift für Naturforschung B. 34 (7): 942–948. doi:10.1515/znb-1979-0713. ISSN 1865-7117. S2CID 94076732.
  35. ↑ Liese, Werner; Dehnicke, Kurt; Walker, Ingeborg; Strähle, Joachim (1979-05-01). "Darstellung, Eigenschaften und Kristallstruktur von Rhenium(VII)-Nitridchlorid, ReNCl 4 / Preparation, Properties and Crystal Structure of Rhenium(VII) Nitride Chloride, ReNCl 4". Zeitschrift für Naturforschung B. 34 (5): 693–696. doi:10.1515/znb-1979-0509. ISSN 1865-7117. S2CID 96155024.
  36. 1 2 Binder, Anja; Maichle-Mössmer, Cäcilia; Niquet, Elke; Strähle, Joachim (July 2008). "Synthese und Kristallstruktur der Rhenium(VII)-Nitridchloride ReNCl4 und ReNCl4·H2O". Zeitschrift für anorganische und allgemeine Chemie (in German). 634 (8): 1326–1328. doi:10.1002/zaac.200800057.
  37. ↑ Abram, Ulrich; Braun, Martin; Abram, Sonja; Kirmse, Reinhard; Voigt, Andreas (1998). "[NBu4][ReNCl4]: Facile synthesis, structure, electron paramagnetic resonance spectroscopy and reactions". Journal of the Chemical Society, Dalton Transactions (2): 231–238. doi:10.1039/a705881k.
  38. ↑ "Kleinite Mineral Data". www.webmineral.com. Retrieved 2023-08-31.
  39. ↑ "Mosesite Mineral Data". www.webmineral.com. Retrieved 2023-08-31.
  40. ↑ Wang, Naizhou; Ye, Guojun; Hu, Guobing; Meng, Fanbao; Shang, Chao; Shi, Mengzhu; Ying, Jianjun; Chen, Xianhui (2019-08-05). "Absence of van der Waals Gap in Ternary Thorium Nitride ThNF and ThNCl". Inorganic Chemistry. 58 (15): 9897–9903. doi:10.1021/acs.inorgchem.9b01050. ISSN 0020-1669. PMID 31291102. S2CID 195879442.
  41. ↑ Nakamura, Akio; Akabori, Mitsuo; Ogawa, Toru; Huntelaar, M. (April 2005). "Uranium nitride chloride UNCl: 30K-class ferromagnet with layered structure". Physica B: Condensed Matter. 359–361: 1021–1023. Bibcode:2005PhyB..359.1021N. doi:10.1016/j.physb.2005.01.384.
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