Corundum is the name for a structure prototype in inorganic solids, derived from the namesake polymorph of aluminum oxide (α-Al2O3).[1] Other compounds, especially among the inorganic solids, exist in corundum structure, either in ambient or other conditions. Corundum structures are associated with metal-insulator transition,[2] ferroelectricity,[3] polar magnetism,[4][5] and magnetoelectric effects.

Structure

The corundum structure has the space group R3c. It typically exists in binary compounds of the type A2B3, where A is metallic and B is nonmetallic, including sesquioxides (A2O3),[6] sesquisulfides (A2S3),[7] etc. When A is nonmetallic and B is metallic, the structure becomes the antiphase of corundum, called the anticorundum structure type,[8] with examples including β-Ca3N2[9] and borates. Ternary and multinary compounds can also exists in the corundum structure. The corundum-like structure with the composition A2BB'O6 is called double corundum.[4] A list of examples are tabulated below.

Materials that exist in the corundum structure
Chemical formulaAlternative nameMaterial typeReference
Al2O3α-Al2O3 or corundumOxide[1]
V2O3Oxide[2][10]
Cr2O3α-Cr2O3Oxide[10]
Fe2O3α-Fe2O3 or hematiteOxide[10]
Ga2O3α-Ga2O3Oxide[11]
In2O3rh-In2O3Oxide[12][13]
Ti2O3α-Ti2O3Oxide[14]
Mn2O3ε-Mn2O3Oxide[15]
Rh2O3Oxide[16]
Ir2O3α-Ir2O3Oxide[17]
Tl2O3Oxide[18]
Ca3N2β-Ca3N2Nitride[9]
In2S3ε-In2S3Sulfide[19]
Tm2S3E-Tm2S3 or ε-Tm2S3Sulfide[20]
Yb2S3E-Yb2S3 or ε-Yb2S3Sulfide[21]
Lu2S3E-Lu2S3 or ε-Lu2S3Sulfide[22]
Ca3(BO3)2Borate[23]
Sr3(BO3)2Borate[24]
Eu3(BO3)2Borate[25]
ScFeO3Ferrite[26]
GaFeO3Ferrite[27]
InFeO3Ferrite[28]
CrTiO3Titanate[29]
NiCrO3Chromite[30]
InVO3Vanadate[31]
Ni3TeO6Double oxide[32]
Ni2InSbO6Double oxide[33]
Ni2ScSbO6Double oxide[33]
Mn2FeMoO6Double oxide[34]
Mn2FeWO6Double oxide[35]
Co4Ta2O9Triple oxide[36][37]

See also

References

  1. 1 2 Pauling, Linus; Hendricks, Sterling B. (1925-03-05). "The crystal structures of hematite and corundum". Journal of the American Chemical Society. 47 (3): 781–790. doi:10.1021/ja01680a027. ISSN 0002-7863.
  2. 1 2 Tanaka, Arata (2002). "Electronic Structure and Phase Transition in V2O3 : Importance of 3 d Spin-Orbit Interaction and Lattice Distortion". Journal of the Physical Society of Japan. 71 (4): 1091–1107. arXiv:cond-mat/0201407. Bibcode:2002JPSJ...71.1091T. doi:10.1143/JPSJ.71.1091. ISSN 0031-9015. S2CID 119014386.
  3. ↑ Ye, Meng; Vanderbilt, David (2016-04-04). "Ferroelectricity in corundum derivatives". Physical Review B. 93 (13): 134303. arXiv:1602.03852. Bibcode:2016PhRvB..93m4303Y. doi:10.1103/PhysRevB.93.134303. ISSN 2469-9950. S2CID 56429009.
  4. 1 2 Cai, Guo-Hong; Greenblatt, Martha; Li, Man-Rong (2017-07-11). "Polar Magnets in Double Corundum Oxides". Chemistry of Materials. 29 (13): 5447–5457. doi:10.1021/acs.chemmater.7b01567. ISSN 0897-4756.
  5. ↑ P N, Ravi Shankar; Mishra, Swarnamayee; Athinarayanan, Sundaresan (2020-04-01). "Polar magnetic oxides from chemical ordering: A new class of multiferroics". APL Materials. 8 (4): 040906. Bibcode:2020APLM....8d0906P. doi:10.1063/5.0003305. ISSN 2166-532X. S2CID 216480507.
  6. ↑ Manjón, Francisco; Sans, Juan; Ibáñez, Jordi; Pereira, André (2019-11-28). "Pressure-Induced Phase Transitions in Sesquioxides". Crystals. 9 (12): 630. doi:10.3390/cryst9120630. hdl:10261/197158. ISSN 2073-4352.
  7. ↑ Sleight, Arthur W.; Prewitt, Charles T. (1968). "Crystal chemistry of the rare earth sesquisulfides". Inorganic Chemistry. 7 (11): 2282–2288. doi:10.1021/ic50069a022. ISSN 0020-1669.
  8. ↑ Vegas, Angel (2000). "Cations in Inorganic Solids". Crystallography Reviews. 7 (3): 189–283. doi:10.1080/08893110008044245. ISSN 0889-311X. S2CID 196777970.
  9. 1 2 Höhn, Peter; Hoffmann, Stefan; Hunger, Jens; Leoni, Stefano; Nitsche, Fabian; Schnelle, Walter; Kniep, Rüdiger (2009-03-23). "β-Ca 3 N 2 , a Metastable Nitride in the System Ca-N". Chemistry - A European Journal. 15 (14): 3419–3425. doi:10.1002/chem.200801857. PMID 19212988.
  10. 1 2 3 Sato, Yosiko; Akimoto, Syun-iti (1979). "Hydrostatic compression of four corundum-type compounds: α-Al2O3, V2O3, Cr2O3, and α-Fe2O3". Journal of Applied Physics. 50 (8): 5285. Bibcode:1979JAP....50.5285S. doi:10.1063/1.326625.
  11. ↑ Sinha, G.; Adhikary, K.; Chaudhuri, S. (2005). "Sol–gel derived phase pure α-Ga2O3 nanocrystalline thin film and its optical properties". Journal of Crystal Growth. 276 (1–2): 204–207. Bibcode:2005JCrGr.276..204S. doi:10.1016/j.jcrysgro.2004.11.375.
  12. ↑ Gurlo, Aleksander; Kroll, Peter; Riedel, Ralf (2008-04-07). "Metastability of Corundum-Type In2O3". Chemistry - A European Journal. 14 (11): 3306–3310. doi:10.1002/chem.200701830. PMID 18270987.
  13. ↑ García-Domene, B.; Sans, J. A.; Manjón, F. J.; Ovsyannikov, Sergey V.; Dubrovinsky, L. S.; Martinez-Garcia, D.; Gomis, O.; Errandonea, D.; Moutaabbid, H.; Le Godec, Y.; Ortiz, H. M. (2015-12-31). "Synthesis and High-Pressure Study of Corundum-Type In2O3". The Journal of Physical Chemistry C. 119 (52): 29076–29087. doi:10.1021/acs.jpcc.5b06939. hdl:10251/66258. ISSN 1932-7447.
  14. ↑ Rice, C. E.; Robinson, W. R. (1977-05-15). "High-temperature crystal chemistry of Ti2O3: structural changes accompanying the semiconductor–metal transition". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 33 (5): 1342–1348. doi:10.1107/S0567740877006062.
  15. ↑ Ovsyannikov, Sergey V.; Abakumov, Artem M.; Tsirlin, Alexander A.; Schnelle, Walter; Egoavil, Ricardo; Verbeeck, Jo; Van Tendeloo, Gustaaf; Glazyrin, Konstantin V.; Hanfland, Michael; Dubrovinsky, Leonid (2013-01-28). "Perovskite-like Mn 2 O 3 : A Path to New Manganites". Angewandte Chemie International Edition. 52 (5): 1494–1498. doi:10.1002/anie.201208553. PMID 23280731.
  16. ↑ Coey, J. M. D. (1970-11-01). "The crystal structure of Rh 2 O 3". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 26 (11): 1876–1877. doi:10.1107/S0567740870005022. ISSN 0567-7408.
  17. ↑ Kan, Shin-ichi; Takemoto, Shu; Kaneko, Kentaro; Takahashi, Isao; Sugimoto, Masahiro; Shinohe, Takashi; Fujita, Shizuo (2018-11-19). "Electrical properties of α-Ir2O3 /α-Ga2O3 pn heterojunction diode and band alignment of the heterostructure". Applied Physics Letters. 113 (21): 212104. Bibcode:2018ApPhL.113u2104K. doi:10.1063/1.5054054. ISSN 0003-6951. S2CID 125213796.
  18. ↑ Gomis, O.; Santamaría-Pérez, D.; Ruiz-Fuertes, J.; Sans, J. A.; Vilaplana, R.; Ortiz, H. M.; García-Domene, B.; Manjón, F. J.; Errandonea, D.; Rodríguez-Hernández, P.; Muñoz, A. (2014-10-07). "High-pressure structural and elastic properties of Tl2O3". Journal of Applied Physics. 116 (13): 133521. arXiv:1501.02228. Bibcode:2014JAP...116m3521G. doi:10.1063/1.4897241. hdl:10251/52208. ISSN 0021-8979. S2CID 118564364.
  19. ↑ Range, Klaus-Jürgen; Zabel, Manfred (1978-04-01). "ε-In 2 S 3 , eine Hochdruckmodifikation mit Korundstruktur / ε-In 2 S 3 , a High Pressure Modification with Corundum Type Structure". Zeitschrift für Naturforschung B. 33 (4): 463–464. doi:10.1515/znb-1978-0423. ISSN 1865-7117. S2CID 101110451.
  20. ↑ Range, K. J.; Drexler, H.; Gietl, A.; Klement, U.; Lange, K. G. (1990-03-15). "Tm2S3–V, a corundum-type modification of thulium sesquisulfide". Acta Crystallographica Section C: Crystal Structure Communications. 46 (3): 487–488. doi:10.1107/S0108270189012035.
  21. ↑ Schleid, Thomas; Lissner, Falk (1996-05-01). "A-Pr 2 S 3 , D-Ho 2 S 3 und E-Yb 2 S 3 :Synthese und Einkristallstrukturuntersuchungen / A-Pr 2 S 3 , D-Ho 2 S 3 and E-Yb 2 S 3 :Synthesis and Single Crystal Structure Investigations". Zeitschrift für Naturforschung B. 51 (5): 733–738. doi:10.1515/znb-1996-0519. ISSN 1865-7117. S2CID 94614003.
  22. ↑ Range, Klaus-Jürgen; Leeb, Richard (1975-08-01). "Die Kristallstruktur von Lu2S3 / The Crystal Structure of Lu2S3". Zeitschrift für Naturforschung B. 30 (7–8): 637–638. doi:10.1515/znb-1975-7-835. ISSN 1865-7117. S2CID 97939759.
  23. ↑ Vegas, A. (1985-11-15). "New description of the Ca3(BO3)2 structure". Acta Crystallographica Section C: Crystal Structure Communications. 41 (11): 1689–1690. doi:10.1107/S0108270185009052.
  24. ↑ Richter, L.; Müller, Franz (1980). "Zur Struktur von Sr3B2O6". Zeitschrift für anorganische und allgemeine Chemie (in German). 467 (1): 123–125. doi:10.1002/zaac.19804670114. ISSN 0044-2313.
  25. ↑ Machida, Ken-ichi; Adachi, Gin-ya; Hata, Hajime; Shiokawa, Jiro (1981). "The Crystal Structure and Magnetic Property of Europium(II) Orthoborate". Bulletin of the Chemical Society of Japan. 54 (4): 1052–1055. doi:10.1246/bcsj.54.1052. ISSN 0009-2673.
  26. ↑ Li, Man-Rong; Adem, Umut; McMitchell, Sean R. C.; Xu, Zhongling; Thomas, Chris I.; Warren, John E.; Giap, Duong V.; Niu, Hongjun; Wan, Xinming; Palgrave, Robert G.; Schiffmann, Florian (2012-02-29). "A Polar Corundum Oxide Displaying Weak Ferromagnetism at Room Temperature". Journal of the American Chemical Society. 134 (8): 3737–3747. doi:10.1021/ja208395z. ISSN 0002-7863. PMC 3693400. PMID 22280499.
  27. ↑ Niu, Hongjun; Pitcher, Michael J.; Corkett, Alex J.; Ling, Sanliang; Mandal, Pranab; Zanella, Marco; Dawson, Karl; Stamenov, Plamen; Batuk, Dmitry; Abakumov, Artem M.; Bull, Craig L. (2017-02-01). "Room Temperature Magnetically Ordered Polar Corundum GaFeO 3 Displaying Magnetoelectric Coupling". Journal of the American Chemical Society. 139 (4): 1520–1531. doi:10.1021/jacs.6b11128. hdl:10067/1475070151162165141. ISSN 0002-7863. PMID 28013545.
  28. ↑ Prewitt, Charles T.; Shannon, Robert D.; Rogers, Donald Burl; Sleight, Arthur W. (1969). "C rare earth oxide-corundum transition and crystal chemistry of oxides having the corundum structure". Inorganic Chemistry. 8 (9): 1985–1993. doi:10.1021/ic50079a033. ISSN 0020-1669.
  29. ↑ Reid, A.F.; Sabine, T.M.; Wheeler, D.A. (1972). "Neutron diffraction and other studies of magnetic ordering in phases based on Cr2O3, V2O3 and Ti2O3". Journal of Solid State Chemistry. 4 (3): 400–409. Bibcode:1972JSSCh...4..400R. doi:10.1016/0022-4596(72)90155-7.
  30. ↑ Chamberland, B. L.; Cloud, W. H. (1969). "Preparation and Properties of NiCrO 3". Journal of Applied Physics. 40 (1): 434–435. Bibcode:1969JAP....40..434C. doi:10.1063/1.1657087. ISSN 0021-8979.
  31. ↑ Tan, Zhenhong; Lussier, Joey A.; Yamada, Takumi; Xu, Yuanhui; Saito, Takashi; Goto, Masato; Kosugi, Yoshihisa; Vrublevskiy, Dmitry; Kanemitsu, Yoshihiko; Bieringer, Mario; Shimakawa, Yuichi (2022-06-20). "LiNbO3‐Type Polar Antiferromagnet InVO3 Synthesized under High‐Pressure Conditions". Angewandte Chemie International Edition. 61 (25): e202203669. doi:10.1002/anie.202203669. ISSN 1433-7851. PMID 35384197. S2CID 247977639.
  32. ↑ Newnham, R.E.; Meagher, E.P. (1967). "Crystal structure of Ni3TeO6". Materials Research Bulletin. 2 (5): 549–554. doi:10.1016/0025-5408(67)90031-1.
  33. 1 2 Ivanov, S. A.; Mathieu, R.; Nordblad, P.; Tellgren, R.; Ritter, C.; Politova, E.; Kaleva, G.; Mosunov, A.; Stefanovich, S.; Weil, M. (2013-03-26). "Spin and Dipole Ordering in Ni 2 InSbO 6 and Ni 2 ScSbO 6 with Corundum-Related Structure". Chemistry of Materials. 25 (6): 935–945. arXiv:1304.0474. doi:10.1021/cm304095s. ISSN 0897-4756. S2CID 104418969.
  34. ↑ Li, Man-Rong; Retuerto, Maria; Walker, David; Sarkar, Tapati; Stephens, Peter W.; Mukherjee, Swarnakamal; Dasgupta, Tanusri Saha; Hodges, Jason P.; Croft, Mark; Grams, Christoph P.; Hemberger, Joachim (2014-09-26). "Magnetic-Structure-Stabilized Polarization in an Above-Room-Temperature Ferrimagnet". Angewandte Chemie International Edition. 53 (40): 10774–10778. doi:10.1002/anie.201406180. PMID 25131837.
  35. ↑ Li, Man-Rong; Croft, Mark; Stephens, Peter W.; Ye, Meng; Vanderbilt, David; Retuerto, Maria; Deng, Zheng; Grams, Christoph P.; Hemberger, Joachim; Hadermann, Joke; Li, Wen-Min (2015-02-11). "Mn2FeWO6 : A New Ni3TeO6-Type Polar and Magnetic Oxide". Advanced Materials. 27 (13): 2177–2181. doi:10.1002/adma.201405244. PMID 25677612. S2CID 42614520.
  36. ↑ Bertaut, E.F.; Corliss, L.; Forrat, F.; Aleonard, R.; Pauthenet, R. (1961). "Etude de niobates et tantalates de metaux de transition bivalents". Journal of Physics and Chemistry of Solids (in French). 21 (3–4): 234–251. Bibcode:1961JPCS...21..234B. doi:10.1016/0022-3697(61)90103-2.
  37. ↑ Chaudhary, S.; Srivastava, P.; Kaushik, S.D.; Siruguri, V.; Patnaik, S. (2019-04-01). "Nature of magnetoelectric coupling in corundum antiferromagnet Co4Ta2O9". Journal of Magnetism and Magnetic Materials. 475: 508–513. arXiv:1707.03127. Bibcode:2019JMMM..475..508C. doi:10.1016/j.jmmm.2018.09.071. S2CID 119445458.
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