一磷化钛

一磷化钛
别名	磷化钛(III)
识别
CAS号	12037-65-9
PubChem	82856
SMILES	P#[Ti];
InChI	1S/P.Ti;
EINECS	234-862-6
性质
化学式	TiP
	78.841 g·mol⁻¹
外观	灰色晶体
密度	4.08 g/cm³（固）[1]
熔点	>1400°C [1]
结构
晶体结构	六方晶系
危险性
欧盟分类	未列出
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

一磷化钛（化学式：TiP）是一种无机化合物，通常为灰色粉末。[1]它是有着高熔点的金属导体。[2]它对水或通常的酸稳定。[1]它的性质和碱金属或碱土金属含P³⁻的磷化物（如Na₃P）相比是不同的，那些磷化物不具备金属性，且会理科水解。[2]一磷化钛被分类为“富金属磷化物”，有着多余的来自金属的离域价电子。[2]

TiP可以通过TiCl₄和PH₃的反应制备。[1]

钛的其它磷化物，如Ti₃P、[3]Ti₂P、[4]Ti₇P₄、[5]Ti₅P₃、[6]和Ti₄P₃[7]等，是已知的。

参考文献

D.L. Perry S.L. Phillips (1995) Handbook of inorganic compounds CRC Press ISBN 0-8493-8671-3
H.G. Von Schnering, W. Hönle Phosphides - Solid state chemistry Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons ISBN 0-471-93620-0
Hydrogen absorption in Ti₃P Halter U., Mrowietz M., Weiss A Journal of the less-common metals 1986 118 343-348
Structure of Ti₂P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy M. Gemmi, X. D. Zou, S. Hovmöller, A. Migliori, M. Vennström and Y. Andersson Acta Crystallogr. (2003). A59, 117-126 doi:10.1107/S0108767302022559 PMID 12604849
New Phases in the Ti-P and Ti-Cu-P Systems, Carrillo C W., Lundström T Acta Chem.Scand., Series A: (1979), 33, 401-402
Crystal Structure Refinement of Ti₅P₃ Carrillo C W., Lundström T Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry 1980 34 415-419
Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP₂ and ZrP₂, Snell P.O, Acta Chem. Scand. 1968 22 1942-1952

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.

[Perry-1] D.L. Perry S.L. Phillips (1995) Handbook of inorganic compounds CRC Press ISBN 0-8493-8671-3

[Schnering-2] H.G. Von Schnering, W. Hönle Phosphides - Solid state chemistry Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons ISBN 0-471-93620-0

[3] Hydrogen absorption in Ti₃P Halter U., Mrowietz M., Weiss A Journal of the less-common metals 1986 118 343-348

[4] Structure of Ti₂P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy M. Gemmi, X. D. Zou, S. Hovmöller, A. Migliori, M. Vennström and Y. Andersson Acta Crystallogr. (2003). A59, 117-126 doi:10.1107/S0108767302022559 PMID 12604849

[5] New Phases in the Ti-P and Ti-Cu-P Systems, Carrillo C W., Lundström T Acta Chem.Scand., Series A: (1979), 33, 401-402

[6] Crystal Structure Refinement of Ti₅P₃ Carrillo C W., Lundström T Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry 1980 34 415-419

[7] Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP₂ and ZrP₂, Snell P.O, Acta Chem. Scand. 1968 22 1942-1952