溴化锫

溴化锫
识别
CAS号	22787-71-9
SMILES	[Br-].[Br-].[Br-].[Bk+3];
性质
化学式	BkBr3
摩尔质量	486.71 g·mol−1
外观	黄绿色晶体[1]
相关物质
其他阴离子	三氟化锫; 氯化锫; 碘化锫
其他阳离子	溴化锔; 溴化锎
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

溴化锫是锫的溴化物，化学式 BkBr₃。

结构

溴化锫在低温下是PuBr₃结构的，为正交晶系，晶格参数 a = 403 pm、b = 1271 pm 和c = 912 pm。[2]在高温下，溴化锫呈AlCl₃结构，为单斜晶系，晶格参数 a = 723 pm、b = 1253 pm、c = 683 pm 和β = 110.6°。[2][3][4][5]

参考资料

Holleman, Arnold Frederik; Wiberg, Egon, Wiberg, Nils , 编, , 由Eagleson, Mary; Brewer, William翻译, San Diego/Berlin: Academic Press/De Gruyter, 2001, ISBN 0-12-352651-5
John H. Burns, J. R. Peterson, J. N. Stevenson: Crystallographic Studies of some Transuranic Trihalides: ²³⁹PuCl₃, ²⁴⁴CmBr₃, ²⁴⁹BkBr₃ and ²⁴⁹CfBr₃, in: J. Inorg. Nucl. Chem., 1975, 37 (3), S. 743–749 (doi:10.1016/0022-1902(75)80532-X).
J. P. Young, R. G. Haire, J. R. Peterson, D. D. Ensor, R. L. Fellows: Chemical Consequences of Radioactive Decay. 1. Study of ²⁴⁹Cf Ingrowth into Crystalline ²⁴⁹BkBr₃: A New Crystalline Phase of CfBr₃, in: Inorg. Chem., 1980, 19 (8), S. 2209–2212 (doi:10.1021/ic50210a003).
D. Cohen, S. Fried, S. Siegel, B. Tani: The preparation and crystal structure of some berkelium compounds, in: Inorg. Nucl. Chem. Lett., 1968, 4 (5), S. 257–260 (doi:10.1016/0020-1650(68)80125-4).
J. R. Peterson, D. E. Hobart: The Chemistry of Berkelium, in: Harry Julius Emeleus (Hrsg.): Advances in Inorganic Chemistry and Radiochemistry, Volume 28, Academic Press, 1984, ISBN 0-12023628-1, S. 29–64 (doi:10.1016/S0898-8838(08)60204-4), hier: S. 52–53 (溴化锫，第52頁，載於Google圖書.

扩展阅读

David E. Hobart, Joseph R. Peterson: Berkelium （页面存档备份，存于）, in: Lester R. Morss, Norman M. Edelstein, Jean Fuger (Hrsg.): The Chemistry of the Actinide and Transactinide Elements, Springer, Dordrecht 2006; ISBN 1-4020-3555-1, S. 1444–1498 (doi:10.1007/1-4020-3598-5_10).

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[HOWI_1969-1] Holleman, Arnold Frederik; Wiberg, Egon, Wiberg, Nils , 编, , 由Eagleson, Mary; Brewer, William翻译, San Diego/Berlin: Academic Press/De Gruyter, 2001, ISBN 0-12-352651-5

[Burns_1975-2] John H. Burns, J. R. Peterson, J. N. Stevenson: Crystallographic Studies of some Transuranic Trihalides: ²³⁹PuCl₃, ²⁴⁴CmBr₃, ²⁴⁹BkBr₃ and ²⁴⁹CfBr₃, in: J. Inorg. Nucl. Chem., 1975, 37 (3), S. 743–749 (doi:10.1016/0022-1902(75)80532-X).

[3] J. P. Young, R. G. Haire, J. R. Peterson, D. D. Ensor, R. L. Fellows: Chemical Consequences of Radioactive Decay. 1. Study of ²⁴⁹Cf Ingrowth into Crystalline ²⁴⁹BkBr₃: A New Crystalline Phase of CfBr₃, in: Inorg. Chem., 1980, 19 (8), S. 2209–2212 (doi:10.1021/ic50210a003).

[4] D. Cohen, S. Fried, S. Siegel, B. Tani: The preparation and crystal structure of some berkelium compounds, in: Inorg. Nucl. Chem. Lett., 1968, 4 (5), S. 257–260 (doi:10.1016/0020-1650(68)80125-4).

[5] J. R. Peterson, D. E. Hobart: The Chemistry of Berkelium, in: Harry Julius Emeleus (Hrsg.): Advances in Inorganic Chemistry and Radiochemistry, Volume 28, Academic Press, 1984, ISBN 0-12023628-1, S. 29–64 (doi:10.1016/S0898-8838(08)60204-4), hier: S. 52–53 (溴化锫，第52頁，載於Google圖書.