十钨二钒磷酸
十钨二钒磷酸是一种杂多酸，化学式为H5PW10V2O40。[3]它可以偏钒酸钠、磷酸氢二钠、钨酸钠和硫酸为原料反应制得。[1]它可以被还原剂还原为低价态化合物。[4]它可用作醇和酚无溶剂乙酰化的催化剂。[1]它可被封装进rht-MOF-1的空腔内用于燃料油的脱硫。[5]
| 十钨二钒磷酸 | |
|---|---|
| 英文名 | |
| 识别 | |
| CAS号 | 12398-74-2  |
| 性质 | |
| 化学式 | H5O40PV2W10 |
| 摩尔质量 | 2616.27 g·mol−1 |
| 外观 | 橙红色固体[1] |
| 结构 | |
| 晶体结构 | 立方晶系 O2h-Pn3n（三十水合物）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- Farhadi, Saeid; Taherimehr, Masoumeh. Vanadium-substituted tungstophosphoric acid (H5PV2W10O40): a green and reusable catalyst for highly efficient acetylation of alcohols and phenols under solvent-free conditions （页面存档备份，存于）. Acta Chimica Slovenica, 2008. 55 (3): 637-643.
- Suteu, Alexandru; Mirza, Lucretia. X-ray structural study of triheteropolyacids（法文）. Revue Roumaine de Chimie, 1970. 15 (10): 1563-1572.
- Courtin, Paul. Molybdenum and tungsten heteropolyanions substituted by vanadium(V). II. Compounds with high vanadium content（法文）. Revue de Chimie Minerale, 1971. 8 (2): 221-240.
- Polotebnova, N. A.; Krachun, S. V.; Danilina, L. M. Products of the reduction of tungstovanadophosphoric heteropoly acids（俄文）. Zhurnal Neorganicheskoi Khimii, 1976. 21 (11): 3172-3175.
- Yiyang Bai, Yuxiang Xin, Jiabin Liu, Liqiang Ma, Guangming Li. . Applied Organometallic Chemistry. 2022-05, 36 (5) [2022-09-24]. ISSN 0268-2605. doi:10.1002/aoc.6633. （原始内容存档于2022-09-27） （英语）.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.