正十七烷基苯

正十七烷基苯是一种有机化合物,化学式为C23H40。它可由1-碘十六烷溴化苄三苯基膦和碱存在下反应得到。[3]它在异丙醇中可以被[Na(15-冠-5)]+e-还原为1-十七烷基-1,4-环己二烯。[4]

正十七烷基苯
别名 十七烷基苯
识别
CAS号 14752-75-1  checkY
PubChem 84623
ChemSpider 76342
性质
化学式 C23H40
摩尔质量 316.56 g·mol−1
熔点 19.65 °C(0.1 MPa)[1]
32 °C[2]
沸点 397 °C[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. Michel Milhet et al. Solid−Liquid Equilibria under High Pressure of Nine Pure n-Alkylbenzenes. J. Chem. Eng. Data 2008, 53, 1, 233–237 doi:10.1021/je700529y
  2. "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2023-11-15].
  3. Efficient phosphine-mediated formal C(sp3)–C(sp3) coupling reactions of alkyl halides in batch and flow. Chem Commun. 2017. doi:10.1039/C7CC02033C
  4. Org. Lett. 2018, 20, 12, 3439–3442. doi:10.1021/acs.orglett.8b00891
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