氮化锑

氮化锑是一种无机化合物,化学式为SbN。它可由三氯化锑[1]三碘化锑[2]和液氨为原料反应制得。三氯化锑在氨、氢气、氮气的混合气体中加热,也可以得到氮化锑。[3]理论计算表明,它是一种铁电材料。[4]

氮化锑
IUPAC名
Azanylidynestibane
别名 一氮化锑
识别
CAS号 12333-57-2  checkY
PubChem 72720468
SMILES
 
  • N#[Sb]
InChI
 
  • 1S/N.Sb
InChIKey IBKBIJITWRZZBB-UHFFFAOYSA-N
性质
化学式 SbN
135.767 g·mol¹
外观 橙色
沸点 550 °C(分解)[1]
溶解性 分解[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. Schwarz, Robert; Jeanmaire, Albert. The ammonolysis of antimony trichloride. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen (1932), 65B, 1662-1664. CODEN BDCBAD.
  2. Remy, H.; Tiedemann, G. The behavior of antimony triiodide and of arsenic triiodide in the presence of ammonia. Naturwissenschaften (1960), 47, 178.ISSN 0028-1042
  3. Shiraishi, Tadashi; Yamazaki, Shunpei; Arai, Yasuyuki. Preparation of antimony nitride films. 1987. JP62040377 A.
  4. Liu, Chang; Wan, Wenhui; Ma, Jie; Guo, Wei; Yao, Yugui. . Nanoscale (Royal Society of Chemistry (RSC)). 2018, 10 (17): 7984–7990. ISSN 2040-3364. doi:10.1039/c7nr09006d.
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