溴酸铥
溴酸铥是一种无机化合物,化学式为Tm(BrO3)3。它可由溴酸钾和高氯酸铥在热水中反应,于15 °C过滤除去高氯酸钾后得到;[1]溴酸钡和硫酸铥反应,从溶液中也能结晶出九水合溴酸铥。[2]
溴酸铥 | |
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识别 | |
CAS号 | 97375-20-7(无水) 17786-85-5(九水) |
性质 | |
化学式 | Br3O9Tm |
摩尔质量 | 552.64 g·mol−1 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- J Albertsson; I Elding. (1977). The geometry of the nonaaqualanthanoid(3+) complex in the solid bromates and ethyl sulphates. 33(5), 1460–1469. doi:10.1107/s0567740877006293.
- D. Neogy, R.K. Saha, P.K. Chakrabarti, K.N. Chattopadhyay. The effects of crystal field on Tm3+ in Tm(BrO3)3·9H2O: An experimental and theoretical study. Journal of Physics and Chemistry of Solids. 1996. 57 (11): 1777-1782. doi:10.1016/0022-3697(95)00252-9.
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