猕猴桃碱
猕猴桃碱(英語:)是一种环烯醚萜化合物,由多种植物和动物在自然界中产生。它是第一个被发现的环戊单萜生物碱。[1]它是可从缬草(Valeriana officinalis)根[2]和葛枣猕猴桃(Actinidia polygama)以及几种处于幼虫和成虫阶段的昆虫中提取的化合物之一。[3]猕猴桃碱是一种猫引诱剂,其作用类似于猫薄荷中的活性化合物荆芥内酯。[4]
猕猴桃碱 | |
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IUPAC名 (7S)-4,7-Dimethyl-6,7-dihydro-5H-cyclopenta[c]pyridine | |
识别 | |
CAS号 | 524-03-8 |
PubChem | 68231 |
ChemSpider | 61533 |
SMILES |
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InChI |
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InChIKey | ZHQQRIUYLMXDPP-ZETCQYMHBZ |
Beilstein | 81308 |
ChEBI | 2443 |
KEGG | C09910 |
性质 | |
化学式 | C10H13N |
摩尔质量 | 147.22 g·mol−1 |
熔点 | 25 °C(298 K) |
沸点 | 100 - 103 °C(270 K) |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
某些竹节虫物种,包括Megacrania batesii和津田氏大头䗛(Megacrania tsudai),具有化学防御机制,当受到捕食者威胁时,其前胸腺会分泌含猕猴桃碱的物质。[5]
参考资料
- Tsutsui, Minoru; Tsutsui, Ethel Ashworth. . Chemical Reviews. 1959, 59 (6): 1031–1075. doi:10.1021/cr50030a003.
- Janot MM, Guilhem J, Contz O, Venera G, Cionga E. . Ann. Pharm. Fr. 1979, 37 (9–10): 413–20. PMID 547813. 已忽略未知参数
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) (帮助) - Weibel DB, Oldham NJ, Feld B, Glombitza G, Dettner K, Boland W. . Insect Biochemistry and Molecular Biology. 2001, 31 (6–7): 583–591. PMID 11267897. doi:10.1016/s0965-1748(00)00163-6.
- Lichman, Benjamin R.; Godden, Grant T.; Hamilton, John P.; Palmer, Lira; Kamileen, Mohamed O.; Zhao, Dongyan; Vaillancourt, Brieanne; Wood, Joshua C.; Sun, Miao; Kinser, Taliesin J.; Henry, Laura K. . Science Advances. 2020-05-01, 6 (20): eaba0721. Bibcode:2020SciA....6..721L. ISSN 2375-2548. PMC 7220310 . PMID 32426505. doi:10.1126/sciadv.aba0721 (英语).
- Wu, I-Hsin; Liu, Hsui-Huei; Chen, Yu-Yen; Tsai, Cheng-Lung; Yu, Yi-Ching; Hsiao, Chung-Yi; Yeh, Wen-Bin. . Entomological Science. 2020, 23 (2): 183–192. S2CID 216322536. doi:10.1111/ens.12410.
- Funayama, Shinji; Cordell, Geoffrey A. (编). . . Academic Press. 2015: 233–255.
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