苯并[a]芴
苯并[a]芴是一种稠环芳香烃，化学式为C17H12，它是苯并芴的同分异构体之一。它可以二苯乙炔和1-溴萘（或1-氯萘）为原料合成得到。[2]它和正丁基锂反应后，再与三甲基氯硅烷反应，可以得到11-三甲基硅基-11H-苯并[a]芴。[3]
| 苯并[a]芴[1] | |
|---|---|
![Chemical structure of benzo[a]fluorene](../I/Benzo(a)fluorene.png.webp) | |
![Ball-and-stick model of the benzo[a]fluorene molecule](../I/Benzo(a)fluorene-3D-balls.png.webp) | |
| IUPAC名 11H-Benzo[a]fluorene | |
| 别名 | 1,2-苯并芴 |
| 识别 | |
| CAS号 | 238-84-6  |
| PubChem | 9195 |
| ChemSpider | 8840 |
| SMILES |
|
| InChI |
|
| InChIKey | HKMTVMBEALTRRR-UHFFFAOYAQ |
| EINECS | 205-944-9 |
| RTECS | DF6382000 |
| KEGG | C19343 |
| 性质 | |
| 化学式 | C17H12 |
| 216.277 g·mol⁻¹ | |
| 外观 | 白色固体[2] |
| 密度 | 0.819 g/cm3 |
| 熔点 | 189.5 °C（463 K） |
| 沸点 | 405 °C（678 K） |
| 溶解性（水） | 0.000045 g/L |
| 溶解性 | 可溶于乙醚、苯、氯仿 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- Lide, David R., 87, Boca Raton, Florida: CRC Press: 3–42, 8–119, 1998, ISBN 0-8493-0594-2
- Lee, Che-Wei; Liu, En-Chih; Wu, Yao-Ting. . The Journal of Organic Chemistry (American Chemical Society (ACS)). 2015-10-09, 80 (21): 10446–10456. ISSN 0022-3263. doi:10.1021/acs.joc.5b02111.
- Kawanishi, Kazuyoshi; Yoshida, Tomoyasu; Aoyama, Yoshinori. Polymer compound for light emitting device with excellent luminance life. 2019. JP2019163455.
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