铋化物
铋化物是含Bi3−阴离子的化合物。碱金属的铋化物M3Bi都是已知的,例如铋化钠(Na3Bi)可以由钠和铋的单质在高温、高压下反应得到。[1]
铋化物 | |
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识别 | |
CAS号 | 21879-62-9 |
性质 | |
化学式 | Bi3− |
208.98 g·mol⁻¹ | |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
多元铋化物也有文献报道,例如有着PbClF结构的KCaBi[2]、同时含有-1和-3价Bi的化合物Ba2Cd2.13Bi3O[3]等。
参考文献
- S. A. Kulinich, M. E. Leonova, L. G. Sevast’yanova, et al. High-Pressure Synthesis of Sodium Bismuthide Na3Bi (页面存档备份,存于). Russian Journal of General Chemistry, 1999. 69(5): 681-683
- H. Hirt, H. J. Deiseroth. Crystal structure of potassium calcium bismuthide, KCaBi (页面存档备份,存于). Zeitschrift für Kristallographie, 2003. 218(JG)
- S.-Q. Xia and S. Bobev. Dibarium tricadmium bismuthide(-I,-III) oxide, Ba2Cd3Bi3-δO (页面存档备份,存于). Acta Cryst. (2010). E66, i81 DOI: 10.1107/S1600536810046283
拓展阅读
- Andrew L. Hector, Ivan P. Parkin. Transition Metal Pnictide Synthesis: Self Propagating Reactions Involving Sodium Arsenide, Antimonide and Bismuthide (页面存档备份,存于). Zeitschrift für Naturforschung B, 1994. 49(4)
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