高氯酸铀酰

高氯酸铀酰是一种无机化合物化学式为UO2(ClO4)2,易溶于水。七水合物中[UO2(H2O)5]2+中有五分子的配位水。[1]

高氯酸铀酰

别名 高氯酸双氧铀
识别
CAS号 13093-00-0(无水)  checkY
113350-98-4(七水)  checkY
性质
化学式 UO2(ClO4)2
468.935(无水)
595.047(七水) g·mol¹
外观 黄色晶体粉末(七水)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

制备

高氯酸铀酰可由三氧化铀高氯酸化学计量比反应得到:[2]

UO3 + 2 HClO4 → UO2(ClO4)2 + H2O

参考文献

  1. Nathaniel W. Alcock, Steinar Esperås. Crystal and molecular structure of uranyl diperchlorate heptahydrate. J. Chem. Soc., Dalton Trans., 1977, 893-896. DOI: 10.1039/DT9770000893
  2. E. Hesford, H.A.C. McKay. The extraction of uranyl perchlorate by tri-n-butyl phosphate (TBP). Journal of Inorganic and Nuclear Chemistry, 1960. 13(1-2): 165-173

拓展阅读

  • Vdovenko, V.M. ; Mashirov, L.G. ; Suglobov, D.N. COMPLEXES OF URANYL PERCHLORATE WITH NEUTRAL LIGANDS (in Russian). Doklady Akademii Nauk SSSR (U.S.S.R), 1965. Vol. 163
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