1-芘甲胺

1-芘甲胺是一种有机化合物，化学式为C17H13N。它可由1-芘甲醛、α-氨基-α-甲基苯乙酸钾和DBU在硫酸镁存在下于1,4-二氧六环中加热反应制得，[1]这一转化也能在一种钌配合物催化下，醛和乙酸铵、氨、氢气反应完成。[2]它和三光气反应，可以得到异氰酸-1-芘甲酯。[3]

1-芘甲胺
识别
CAS号 3786-54-7  checkY
SMILES
 
  • NCC1=CC=C2C=CC3=CC=CC=4C=CC1=C2C34
性质
化学式 C17H13N
摩尔质量 231.29 g·mol−1
外观 浅黄色固体[1]
熔点 70—72 °C（343—345 K）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献
  1. Weiqi Cai, et al. Transamination of Aromatic Aldehydes to Primary Arylmethylamines. Org. Lett. 2023. doi:10.1021/acs.orglett.3c01234.
  2. Easily Synthesized Ru Catalyst Efficiently Converts Carbonyl Compounds and Ammonia into Primary Amines. ChemistrySelect, 2020. doi:10.1002/slct.202002795
  3. Han, Mi Jeong; Kang, Yeong Hun; Bae, Eun Jin. Nanocomposite materials for thermoelectric materials including carbon nanotubes modified with polymeric modifiers and flexible thermoelectric material. 2023. KR2023077223.
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