2,3-二甲基-1-丁烯

2,3-二甲基-1-丁烯
识别
CAS号	563-78-0
性质
化学式	C6H12
摩尔质量	84.16 g·mol−1
外观	液体
密度	0.6732 g·cm−3[1]
沸点	55.6 °C（328.8 K）[2]
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

2,3-二甲基-1-丁烯是一种有机化合物，化学式为C₆H₁₂。它可由2,3-二甲基-1,3-丁二烯在催化剂的存在下进行加氢得到。[3]3,3-二甲基-2-丁醇和Burgess试剂反应虽然也会生成2,3-二甲基-1-丁烯，但是会同时产生较多的2,3-二甲基-2-丁烯与少量的3,3-二甲基-1-丁烯[4]。它进一步发生加氢反应，生成2,3-二甲基丁烷。[5]

参考文献

D.B. Brooks, F.L. Howard, H.C. Crafton. (PDF). Journal of Research of the National Bureau of Standards. 1940-01, 24 (1): 33 [2020-01-18]. ISSN 0091-0635. doi:10.6028/jres.024.018. （原始内容存档 (PDF)于2020-12-08）（英语）.
Robert G. Kelso, Kenneth W. Greenlee, John M. Derfer, Cecil E. Boord. . Journal of the American Chemical Society. 1952-01, 74 (2): 287–292 [2020-01-18]. ISSN 0002-7863. doi:10.1021/ja01122a001 （英语）.
Lutz Greb, Pascual Oña-Burgos, Birgitta Schirmer, Stefan Grimme, Douglas W. Stephan, Jan Paradies. . Angewandte Chemie International Edition. 2012-10-01, 51 (40): 10164–10168 [2020-01-18]. doi:10.1002/anie.201204007 （英语）.
Taibi, Pascale; Mobashery, Shahriar; Hart, Amy C. (Methoxycarbonylsulfamoyl)triethylammonium hydroxide. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2008. pp 1-9. ISBN 978-0-470-84289-8.
Laufenberg, Alfred; Behr, Arno; Keim, Wilhelm. Hydrogenation of aromatics, aldehydes, olefins, nitroalkanes, nitriles, and chlorohydrocarbons using metal salt catalysts in phase-transfer systems. 1989. DE 3841698 A1.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.

[1] D.B. Brooks, F.L. Howard, H.C. Crafton. (PDF). Journal of Research of the National Bureau of Standards. 1940-01, 24 (1): 33 [2020-01-18]. ISSN 0091-0635. doi:10.6028/jres.024.018. （原始内容存档 (PDF)于2020-12-08）（英语）.

[2] Robert G. Kelso, Kenneth W. Greenlee, John M. Derfer, Cecil E. Boord. . Journal of the American Chemical Society. 1952-01, 74 (2): 287–292 [2020-01-18]. ISSN 0002-7863. doi:10.1021/ja01122a001 （英语）.

[3] Lutz Greb, Pascual Oña-Burgos, Birgitta Schirmer, Stefan Grimme, Douglas W. Stephan, Jan Paradies. . Angewandte Chemie International Edition. 2012-10-01, 51 (40): 10164–10168 [2020-01-18]. doi:10.1002/anie.201204007 （英语）.

[4] Taibi, Pascale; Mobashery, Shahriar; Hart, Amy C. (Methoxycarbonylsulfamoyl)triethylammonium hydroxide. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2008. pp 1-9. ISBN 978-0-470-84289-8.

[5] Laufenberg, Alfred; Behr, Arno; Keim, Wilhelm. Hydrogenation of aromatics, aldehydes, olefins, nitroalkanes, nitriles, and chlorohydrocarbons using metal salt catalysts in phase-transfer systems. 1989. DE 3841698 A1.