2,3-二甲基-2,3-丁二胺
2,3-二甲基-2,3-丁二胺是一种有机化合物,化学式为C6H16N2。它可由2,3-二硝基-2,3-二甲基丁烷在盐酸溶液中由锡还原得到。[3]它和苯甲醛反应,可以得到2-苯基-4,4,5,5-四甲基咪唑啉。[4]它和金属盐反应可以形成配合物。[5][6][7]
2,3-二甲基-2,3-丁二胺 | |
---|---|
别名 | 1,1,2,2-四甲基乙二胺 |
识别 | |
CAS号 | 20485-44-3 |
SMILES |
|
性质 | |
化学式 | C6H16N2 |
摩尔质量 | 116.2 g·mol−1 |
密度 | 0.860±0.06 g·cm−3(20 °C)[1] |
熔点 | 97—98 °C(370—371 K)[2] |
沸点 | 147—148 °C(420—421 K)[2] |
溶解性(水) | 28.7 g(25 °C)[1] |
pKa | 10.06±0.25(25 °C)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFindern. [2021-01-26].
- Fred Basolo, R. Kent Murmann, Yun Ti Chen. . Journal of the American Chemical Society. 1953-03, 75 (6): 1478–1480 [2021-01-26]. ISSN 0002-7863. doi:10.1021/ja01102a507 (英语).
- Enrique Huang Kwan, Hayato Ogawa, Makoto Yamashita. . ChemCatChem. 2017-07-07, 9 (13): 2457–2462 [2021-01-26]. doi:10.1002/cctc.201700384 (英语).
- Hirel, Catherine; Vostrikova, Kira E.; Pecaut, Jacques; Ovcharenko, Victor I.; Rey, Paul. Nitronyl and imino nitroxides: improvement of Ullman's procedure and report on a new efficient synthetic route. Chemistry - A European Journal, 2001. 7 (9): 2007-2014. ISSN: 0947-6539. DOI: doi:10.1002/1521-3765(20010504)7:9<2007::AID-CHEM2007>3.0.CO;2-7
- Sean E. Clapham, Robert H. Morris. . Organometallics. 2005-02, 24 (4): 479–481 [2021-01-26]. ISSN 0276-7333. doi:10.1021/om048998k (英语).
- Lutz Dahlenburg, Dagmar Kramer, Frank W. Heinemann. . Journal of Coordination Chemistry. 2010-07-20, 63 (14-16): 2673–2684 [2021-01-26]. ISSN 0095-8972. doi:10.1080/00958971003746108 (英语).
- Siqing Cheng, Xiancheng Zeng, Jiaqing Xie, Shenxin Li. . Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 2002-09-26, 32 (8): 1419–1432 [2021-01-26]. ISSN 0094-5714. doi:10.1081/SIM-120014859 (英语).
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.