2,6-二苯基吡啶

2,6-二苯基吡啶是一种有机化合物，化学式为C17H13N。

2,6-二苯基吡啶
识别
CAS号 3558-69-8  checkY
SMILES
 
  • N=1C(=CC=CC1C=2C=CC=CC2)C=3C=CC=CC3
性质
化学式 C17H13N
摩尔质量 231.29 g·mol−1
熔点 80-81 °C[1]
沸点 190 °C（2.5 mmHg）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

合成与反应

2,6-二苯基吡啶可由2,6-二溴吡啶和苯硼酸在碳酸钾存在下、钯配合物催化下反应制得。[2][3]

它在乙醇中可以被钠还原为2,6-二苯基哌啶。[1]

参考文献
  1. C. G. Overberger, Joseph G. Lombardino and Richard G. Hiskey. J. Am. Chem. Soc. 1957. 79 (24). doi:10.1021/ja01581a020.
  2. Stereoelectronic Flexibility of Ammonium-Functionalized Triazole-Derived Carbenes: Palladation and Catalytic Activities in Water. Organometallics, 2018. doi:10.1021/acs.organomet.8b00347
  3. The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} - A Highly Active Suzuki-Miyaura Catalyst with Excellent Functional Group Tolerance. Advanced Synthesis & Catalysis, 2010. doi:10.1002/adsc.200900848.
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