2-氰基-3-(4-硝基苯基)丙烯酸甲酯
2-氰基-3-(4-硝基苯基)丙烯酸甲酯是一种有机化合物,化学式为C11H8N2O4。它可由4-硝基苯甲醛和氰乙酸甲酯在哌啶催化下于甲醇中反应得到。[3]它和氯气发生加成反应,得到α,β-二氯-α-氰基-4-硝基苯丙酸甲酯。[4]
2-氰基-3-(4-硝基苯基)丙烯酸甲酯 | |
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别名 | α-氰基对硝基肉桂酸甲酯 |
识别 | |
CAS号 | 62985-31-3 42348-04-9(2E) 14479-59-5(Z) |
性质 | |
化学式 | C11H8N2O4 |
232.19 g·mol⁻¹ | |
熔点 | 172—173 °C(445—446 K)[1] 178 °C(451 K)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- Lange, J.; Rump, S.; Galecka, E.; Ilczuk, I.; Lechowska-Postek, M.; Rabsztyn, T.; Szymanska, T.; Walczyna, K. Synthesis and properties of new cyclic derivatives of succinic acid with anticonvulsant activity. Pharmazie, 1977. 32 (2): 82-84. ISSN: 0031-7144.
- Saeed Balalaie, Morteza Bararjanian, Shohreh Hekmat, Peyman Salehi. . Synthetic Communications. 2006-08-01, 36 (17): 2549–2557 [2021-05-17]. ISSN 0039-7911. doi:10.1080/00397910600781471 (英语).
- Katie M. Herbert, Patrick T. Getty, Neil D. Dolinski, Jerald E. Hertzog, Derek de Jong, James H. Lettow, Joy Romulus, Jonathan W. Onorato, Elizabeth M. Foster, Stuart J. Rowan. . Chemical Science. 2020, 11 (19): 5028–5036 [2021-05-17]. ISSN 2041-6520. doi:10.1039/D0SC00605J (英语).
- Zvi Rappoport, Bianca Avramovitch. . The Journal of Organic Chemistry. 1982-04, 47 (8): 1397–1408 [2021-05-17]. ISSN 0022-3263. doi:10.1021/jo00347a003 (英语).
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