2-癸酮
2-癸酮是一种酮类有机物，化学式为C10H20O。它可由2-癸醇的氧化反应制得。[4][5]在氯化二茂钛催化下，它和烯丙基溴发生巴比耶类反应，可以得到4-甲基-1-十二烯-4-醇。[6]
| 2-Decanone | |
|---|---|
 | |
| 别名 | Decan-2-one Methyl octyl ketone |
| 识别 | |
| CAS号 | 693-54-9  |
| PubChem | 12741 |
| ChemSpider | 12218 |
| SMILES |
|
| Beilstein | 1747463 |
| ChEBI | 77929 |
| 性质 | |
| 化学式 | C10H20O |
| 摩尔质量 | 156.27 g·mol−1 |
| 外观 | Liquid; Fatty peachy, aldehyde-like aroma[1] |
| 密度 | 0.821-0.831 (20°)[1] |
| 熔点 | 14 °C[2] |
| 沸点 | 210 °C[1] |
| 溶解性（水） | Insoluble. 0.077 mg/mL at 25 °C[2] |
| 溶解性（Fats and oils） | Soluble[1] |
| log P | 3.73[3] |
| 危险性 | |
GHS危险性符号 | |
| GHS提示词 | 警告 |
| H-术语 | H227, H411 |
| P-术语 | P210, P273, P280, P370+378, P391, P403+235, P501 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- . fao.org. [2023-08-19].
- . Human Metabolome Database. 2012-09-11 [2023-08-19].
- Wishart, D. S.; Tzur, D.; Knox, C.; Eisner, R.; Guo, A. C.; Young, N.; Cheng, D.; Jewell, K.; Arndt, D.; Sawhney, S.; Fung, C.; Nikolai, L.; Lewis, M.; Coutouly, M.-A.; Forsythe, I.; Tang, P.; Shrivastava, S.; Jeroncic, K.; Stothard, P.; Amegbey, G.; Block, D.; Hau, David. D.; Wagner, J.; Miniaci, J.; Clements, M.; Gebremedhin, M.; Guo, N.; Zhang, Y.; Duggan, G. E.; MacInnis, G. D.; Weljie, A. M.; Dowlatabadi, R.; Bamforth, F.; Clive, D.; Greiner, R.; Li, L.; Marrie, T.; Sykes, B. D.; Vogel, H. J.; Querengesser, L. . Nucleic Acids Research (Oxford University Press (OUP)). 2007-01-03, 35 (Database): D521–D526. ISSN 0305-1048. doi:10.1093/nar/gkl923.
- Lee, Donald G.; Ribagorda, María; Adrio, Javier. . . Chichester, UK: John Wiley & Sons, Ltd. 2007-03-15. ISBN 978-0-471-93623-7. doi:10.1002/9780470842898.rp244.pub2.
- Zheng, Zhi; Wang, Jianli; Zhang, Miao; Xu, Lixin; Ji, Jianbing. Magnetic Polystyrene Nanosphere Immobilized TEMPO: A Readily Prepared, Highly Reactive and Recyclable Polymer Catalyst in the Selective Oxidation of Alcohols. ChemCatChem, 2013. 5 (1): 307-312. doi:10.1002/cctc.201200459.
- Unprecedented Barbier-type reactions catalysed by titanocene(III). Chem. Commun., 2004, 2628-2629. doi:10.1039/B411173G.
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