2-硝基乙醇
2-硝基乙醇是一种有机化合物,化学式为NO2CH2CH2OH。它可由硝基甲烷和甲醛在碱性条件下反应制得。[3]其它制备方法还有2-碘乙醇和亚硝酸银的反应[4]及环氧乙烷和亚硝酸钠的反应[5]。它和乙酰氯反应,可以得到乙酸-2-硝基乙酯。[6]
2-硝基乙醇 | |
---|---|
别名 | β-硝基乙醇 |
识别 | |
CAS号 | 625-48-9 |
性质 | |
化学式 | C2H5NO3 |
摩尔质量 | 91.07 g·mol−1 |
密度 | 1.296 g·cm−3[1] |
熔点 | −80 °C[2] |
沸点 | 102 °C(11 Torr)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- Norman Levy, Charles W. Scaife, Arthur E. Wilder Smith. . Journal of the Chemical Society (Resumed). 1946: 1096 [2020-06-28]. ISSN 0368-1769. doi:10.1039/jr9460001096 (英语).
- "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-06-28].
- Madhu Sudan Manna, Santanu Mukherjee. . Journal of the American Chemical Society. 2015-01-14, 137 (1): 130–133 [2020-06-28]. ISSN 0002-7863. doi:10.1021/ja5117556 (英语).
- Wayland E. Noland, Philip J. Hartman. . Journal of the American Chemical Society. 1954-06, 76 (12): 3227–3228 [2020-06-28]. ISSN 0002-7863. doi:10.1021/ja01641a044 (英语).
- Jagat C. Borah, Siddhartha Gogoi, Joshodeep Boruwa, Nabin C. Barua. . Synthetic Communications. 2005-03, 35 (6): 873–878 [2020-06-28]. ISSN 0039-7911. doi:10.1081/SCC-200051043 (英语).
- Colin Philip Leslie. The stereochemistry of the SE2 reaction of pentadienylsilanes [Dissertation], 1994. Department of Chemistry, University of Cambridge. 1630067.
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