3,4'-联吡啶

3,4'-联吡啶是一种有机化合物，化学式为C10H8N2，它是联吡啶的同分异构体之一。它可由4-溴吡啶和3-三丁基锡基吡啶在四(三苯基膦)钯催化下反应制得。[1]

3,4'-联吡啶
识别
CAS号 4394-11-0  checkY
SMILES
 
  • N=1C=CC(=CC1)C=2C=NC=CC2
性质
化学式 C10H8N2
摩尔质量 156.18 g·mol−1
沸点 115 °C（3 torr）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

在钯催化下，4-氯吡啶和3-吡啶硼酸反应[2]，或3-氯吡啶和4-吡啶硼酸反应[3]，都可得到3,4'-联吡啶。

参考文献
  1. Yamamoto, Y., Azuma, Y., & Mitoh, H. (1986). General Method for Synthesis of Bipyridines: Palladium Catalyzed Cross-coupling Reaction of Trimethylstannyl-pyridines with Bromopyridines. Synthesis, 1986(07), 564–565. doi:10.1055/s-1986-31705
  2. Highly efficient Suzuki-Miyaura coupling of heterocyclic substrates through rational reaction design. Chemistry - A European Journal (2008), 14 (14), 4267-4279.
  3. Room-temperature Suzuki-Miyaura coupling of heteroaryl chlorides and tosylates. European Journal of Organic Chemistry (2012), 2012 (31), 6248-6259.
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