4-亚硝基二苯胺

4-亚硝基二苯胺是一种有机化合物,化学式为C12H10N2O。它可由4-亚硝基苯酚苯胺对甲苯磺酸存在下于甲醇中反应得到。[2]催化下,它加氢得到N-苯基对苯二胺[3]它和三异丁基铝反应,可以得到N-苯基-N'-异丁基对苯二胺。[4]

4-亚硝基二苯胺
识别
CAS号 156-10-5  checkY
性质
化学式 C12H10N2O
摩尔质量 198.22 g·mol−1
熔点 143 °C(416 K)[1]
沸点 292 °C(565 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-12-06].
  2. John T. Hays, Herbert Lewis Young, Herbert H. Espy. . The Journal of Organic Chemistry. 1967-01, 32 (1): 158–162 [2022-12-05]. ISSN 0022-3263. doi:10.1021/jo01277a039. (原始内容存档于2022-12-05) (英语).
  3. Starovoitov, M. K.; Kachegin, A. F.; Rudakova, T. V.; Belousov, E. K.; Kozlov, A. I.; Safonov, S. A. Method for preparing 4-(phenylamino)aniline by the catalytic hydrogenation of 4-(phenylamino)nitrosobenzene. 2006 RU 2278108 C2.
  4. Zapevalov, G. A.; Kuz'min, S. V.; Kogan, L. M.; Krol, V. A. Products of the reaction of p-nitrosodiphenylamine with triisobutylaluminum. Doklady Akademii Nauk SSSR, 1984. 274 (2): 335-338. ISSN 0002-3264.
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