亚甲基环己烷

亚甲基环己烷是一种有机化合物，化学式为C7H12，是难溶于水的无色液体。它可由Wittig反应，或由环己酮和Tebbe试剂反应制得。[5][6][7]它和二氧化硫作用，异构为1-甲基环己烯。[8]

亚甲基环己烷
IUPAC名
Methylidenecyclohexane
别名 Methylenecyclohexane
识别
CAS号 1192-37-6  checkY
PubChem 14502
ChemSpider 13846
SMILES
 
  • C=C1CCCCC1
InChI
 
  • 1/C7H12/c1-7-5-3-2-4-6-7/h1-6H2
InChIKey YULMNMJFAZWLLN-UHFFFAOYAJ
性质
化学式 C7H12
96.170 g·mol⁻¹
密度 0.8074 g·cm−3（20 °C）[1]
熔点 −106.7 °C（166.5 K）[2]
沸点 102—103 °C（375—376 K）[3]
溶解性（水） 0.083 g/L[4]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献
  1. Arthur I. Vogel. . Journal of the Chemical Society (Resumed). 1938: 1323 [2019-12-04]. ISSN 0368-1769. doi:10.1039/jr9380001323 （英语）.
  2. "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2019-12-4]
  3. Fawarsky, Al.; Borgmann, I. Isomeric Rearrangement. Berichte der Deutschen Chemischen Gesellschaft, 1908. 40: 4863-4875. ISSN: 0365-9496.
  4. Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-12-4]
  5. Wittig, George; Schoellkopf, U. . Organic Syntheses. 1960, 40: 66 [2019-12-04]. doi:10.15227/orgsyn.040.0066. （原始内容存档于2019-11-07）.
  6. Mark, Herman F. . Hoboken, New Jersey: John Wiley & Sons. 2007: 682 [2019-12-04]. ISBN 978-0-470-04610-4. （原始内容存档于2019-03-06）. I this way, cyclohexanone is transformed into methylenecyclohexene and benzaldehyde into stryene.
  7. Dalton, David R. . John Wiley & Sons. August 4, 2011: 819–820 [2019-12-04]. ISBN 978-1-118-00538-5. （原始内容存档于2019-03-06）. Now, when cyclohexanone is added to the solution in which the [Tebbe] reagent has been generated, reaction occurs to produce methylenecyclohexane and triphenylphosphine oxide
  8. Divakar Masilamani, Edward H. Manahan, John Vitrone, Milorad M. Rogic. . The Journal of Organic Chemistry. 1983-12, 48 (25): 4918–4931 [2019-12-04]. ISSN 0022-3263. doi:10.1021/jo00173a028 （英语）.
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