六氟化钋

六氟化钋（PoF₆）是钋的一种氟化物，也是十八种已知的二元六氟化物之一。它是一种白色不稳定的固体。[1]

制备

曾有化学家试图以如下反应制备它：

\mathrm {Po+3\ F_{2}\longrightarrow PoF_{6}}

1945年时进行了这项实验，但没有成功。预测它的沸点为−40 °C。[2]

PoF₆最终还是由更稳定的钋-208的直接氟化制得。[1]反应形成了一种挥发性氟化物，[3] 但还没有完全表征就分解成四氟化钋了。[4][5]

Holleman, Arnold Frederik; Wiberg, Egon, Wiberg, Nils , 编, , 由Eagleson, Mary; Brewer, William翻译, San Diego/Berlin: Academic Press/De Gruyter: 594, 2001, ISBN 0-12-352651-5
Summary of work to date on volatile neutron source, Monsanto Chemical Company, Unit 3 abstracts of progress reports, August 16–31, 1945; Abstract （页面存档备份，存于）; PDF.
Seppelt, Konrad. . Chemical Reviews. 2015, 115 (2): 1296–1306. PMID 25418862. doi:10.1021/cr5001783.
Weinstock, B., Chernick, C.L.: The preparation of a volatile polonium fluoride. J. Am. Chem. Soc. 82, 4116–4117 (1960)
. January 1962 [2021-04-17]. ISBN 9780080578538. （原始内容存档于2021-04-23）.

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