硫代乙酸-O-乙酯

硫代乙酸-O-乙酯
识别
CAS号	926-67-0
PubChem	136711
性质
化学式	C4H8OS
摩尔质量	104.17 g·mol−1
熔点	105~109 °C[1]
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

硫代乙酸-O-乙酯是一种有机化合物，化学式为CH₃C(S)OC₂H₅。它可由1-乙氧基乙亚胺和硫化氢在无水甲醇中反应制得，[2]或由原乙酸三乙酯和硫化氢在氯化铁或氯化锌催化下反应得到。[1]它和4-氯-3-喹啉胺、正丁基锂（或乙基溴化镁）在四氢呋喃中反应，可以得到2-甲基噻唑并[4,5-c]喹啉。[3]

参考文献

Ohno, A.; Koizumi, T.; Tsuchihashi, G. . Tetrahedron Letters. 1968, 9 (17): 2083–2085. doi:10.1016/S0040-4039(00)89748-8.
Couture, Axel; Grandclaudon, Pierre; Huguerre, Eric. A facile and concise synthesis of 2-alkyl- and 2-aryl-4-oxo-4H-thiopyrano[2,3-b]pyridines. Synthesis, 1989. 6: 456-457. doi:10.1055/s-1989-27288
Couture, Axel; Grandclaudon, Pierre; Ionescu, Dumitru; Ivan, Lucia. . Phosphorus, Sulfur, and Silicon and the Related Elements. 1995, 101 (1-4): 173–177. ISSN 1042-6507. doi:10.1080/10426509508042514.

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[ref-1] Ohno, A.; Koizumi, T.; Tsuchihashi, G. . Tetrahedron Letters. 1968, 9 (17): 2083–2085. doi:10.1016/S0040-4039(00)89748-8.

[2] Couture, Axel; Grandclaudon, Pierre; Huguerre, Eric. A facile and concise synthesis of 2-alkyl- and 2-aryl-4-oxo-4H-thiopyrano[2,3-b]pyridines. Synthesis, 1989. 6: 456-457. doi:10.1055/s-1989-27288

[3] Couture, Axel; Grandclaudon, Pierre; Ionescu, Dumitru; Ivan, Lucia. . Phosphorus, Sulfur, and Silicon and the Related Elements. 1995, 101 (1-4): 173–177. ISSN 1042-6507. doi:10.1080/10426509508042514.