环己基碘

环己基碘是一种有机化合物，化学式为C6H11I。可由环己醇和氢碘酸加热反应制得，[4]或由环己烯和碘化氢反应得到[5]，反应中的碘化氢可由碘化钾和磷酸替代[6]。环己基溴和氢碘酸的卤素交换也会生成环己基碘。[7]

环己基碘
英文名
别名 碘代环己烷
NSC 6075
识别
CAS号 626-62-0  checkY
SMILES
 
  • C1CCCCC1I
性质
化学式 C6H11I
摩尔质量 210.06 g·mol−1
密度 1.624 g·cm−3（20 °C）[1]
熔点 52 °C（325 K）[2]
沸点 180—183 °C（453—456 K）[3]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献
  1. Arthur I. Vogel. Iodides and bromides from alcohols. 1944. GB 565452.
  2. Robert Truffault. Phosphoric anhydride as a catalyst for the polymerization of unsaturated hydrocarbons. A decahydrobiphenyl obtained by dimerization of cyclohexene. Bulletin de la Societe Chimique de France, Memoires, 1936. 3: 442-459. ISSN: 0366-3132.
  3. B. Lecea, J.M. Aizpurua, C. Palomo. . Tetrahedron. 1985-01, 41 (20): 4657–4665 [2019-12-04]. doi:10.1016/S0040-4020(01)82361-9 （英语）.
  4. Doya, Masaharu; Hoshino, Yuki. Preparation of iodine compounds by alcohol iodination using hydriodic acid while removing generated water. Jpn. Kokai Tokkyo Koho, 2010. JP 2010159223 A
  5. Breton, Gary W.; Kropp, Paul J.; Harvey, Ronald G. Hydrogen iodide. e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001.
  6. . Organic Syntheses. 1951, 31: 66 [2019-12-04]. doi:10.15227/orgsyn.031.0066. （原始内容存档于2018-06-02）.
  7. Mohammad Namavari, N. Satyamurthy, Michael E. Phelps, Jorge R. Barrio. . Tetrahedron Letters. 1990-01, 31 (35): 4973–4976 [2019-12-04]. doi:10.1016/S0040-4039(00)97781-5. （原始内容存档于2018-07-02） （英语）.
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