苯六酚

苯六酚，又称六羟基苯，是一种有机化合物，化学式为C6H6O6或C6(OH)6。它是苯的六羟基取代物。[1][2]

苯六酚
IUPAC名
benzene-1,2,3,4,5,6-hexol
别名 hexahydroxybenzene
识别
CAS号 608-80-0  checkY
PubChem 69102
ChemSpider 62319
SMILES
 
  • c1ccccc1O)O)O)O)O)O
InChI
 
  • 1/C6H6O6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h7-12H
InChIKey VWPUAXALDFFXJW-UHFFFAOYAU
性质
化学式 C6H6O6
174.11 g·mol⁻¹
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苯六酚是一种可溶于热水的晶体，[3]熔点大于310°C。[1]它可以用肌醇（环己六醇）来制备。苯六酚氧化生成四羟基对苯醌（THBQ）、玫棕酸和十二羟基环己烷。[4]相反地，苯六酚可由二氯化锡的盐酸溶液还原对四羟基苯醌的钠盐制得。[5]

参考资料
  1. A. J. Fatiadi and W. F. Sager (1973), Hexahydroxybenzene [Benzenehexol] Organic Syntheses, Coll. Vol. 5, p. 595
  2. Gerd Leston(1996), (Polyhydroxy)benzenes. In Kirk‑Othmer Encyclopedia of Chemical Technology, John Wiley & Sons. doi:10.1002/0471238961.1615122512051920.a01
  3. J.I.G. Codagan, John Buckingham, Finlay J. MacDonald, P. H. Rhodes (1996), Dictionary of organic compounds. CRC Press. 9000 pages. ISBN 0-412-54090-8, ISBN 978-0-412-54090-5.
  4. Alexander J. Fatiadi; Horace S. Isbell, William F. Sager. (PDF). Journal of Research of the National Bureau of Standards A: Physics and Chemistry. March–April 1963, 67A (2): 153–162. （原始内容 (PDF)存档于2009-03-25）.
  5. Sandeep Kumar (2006), Self-organization of disc-like molecules: chemical aspects. Chem. Soc. Rev., volume 35, 83–109. doi:10.1039/b506619k
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