Gallium(III) cyanide

Gallium(III) cyanide
Names
	Other names Gallium tricyanide;
Identifiers
3D model (JSmol)	Interactive image;
ChemSpider	10004244;
PubChem CID	21122422;
	InChI InChI=1S/3CN.Ga/c31-2;/q3-1;+3 Key: LRRAVXULCHBNIH-UHFFFAOYSA-N;
	SMILES [C-]#N.[C-]#N.[C-]#N.[Ga+3];
Properties
Chemical formula	Ga(CN)3
Molar mass	147.78 g/mol
Appearance	White solid
Melting point	450 °C (842 °F; 723 K) (decomposes)
Solubility in water	Reacts
Solubility	Soluble in THF and DMF, insoluble in hexane
Structure
Crystal structure	Cubic
Space group	Pm3m
Lattice constant	a = 5.295 Å α = 90°, β = 90°, γ = 90°
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Gallium(III) cyanide is a chemical compound of gallium with the formula Ga(CN)₃. It is an air-sensitive white solid that decomposes at 450 °C.^[1]

Production and reactions

Gallium(III) cyanide is produced by the reaction of gallium(III) chloride and trimethylsilyl cyanide at 75 °C:^[1]

3 Me₃SiCN + GaCl₃ → 3 Me₃SiCl + Ga(CN)₃

The tetracyanogallate(III) ion can be produced by the reaction of Ga(CN)₃ and LiCN or CuCN. It also forms adducts with pyridine to produce Ga(CN)₃(NC₅H₅)₂.^[1]^[3]

References

1 2 3 4 5 6 Louis C. Brousseau; Darrick Williams; J. Kouvetakis; M. O'Keeffe (1997). "Synthetic Routes to Ga(CN)3 and MGa(CN)4 (M = Li, Cu) Framework Structures". Journal of the American Chemical Society. 119 (27): 6292–6296. doi:10.1021/ja9702024.
↑ D.J. Williams; D.E. Partin; F.J. Lincoln; J. Kouvetakis; M. O'Keeffe (1997). "The Disordered Crystal Structures of Zn(CN)2and Ga(CN)3". Journal of Solid State Chemistry. 134 (1): 164–169. Bibcode:1997JSSCh.134..164W. doi:10.1006/jssc.1997.7571.
↑ A. V. G. Chizmeshya; C. J. Ritter; T. L. Groy; J. B. Tice; J. Kouvetakis (2007). "Synthesis of Molecular Adducts of Beryllium, Boron, and Gallium Cyanides: Theoretical and Experimental Correlations between Solid-State and Molecular Analogues". Chemistry of Materials. 19 (24): 5890–5901. doi:10.1021/cm071275h.

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[syn-1] 1 2 3 4 5 6 Louis C. Brousseau; Darrick Williams; J. Kouvetakis; M. O'Keeffe (1997). "Synthetic Routes to Ga(CN)3 and MGa(CN)4 (M = Li, Cu) Framework Structures". Journal of the American Chemical Society. 119 (27): 6292–6296. doi:10.1021/ja9702024.

[stru-2] D.J. Williams; D.E. Partin; F.J. Lincoln; J. Kouvetakis; M. O'Keeffe (1997). "The Disordered Crystal Structures of Zn(CN)2and Ga(CN)3". Journal of Solid State Chemistry. 134 (1): 164–169. Bibcode:1997JSSCh.134..164W. doi:10.1006/jssc.1997.7571.

[3] A. V. G. Chizmeshya; C. J. Ritter; T. L. Groy; J. B. Tice; J. Kouvetakis (2007). "Synthesis of Molecular Adducts of Beryllium, Boron, and Gallium Cyanides: Theoretical and Experimental Correlations between Solid-State and Molecular Analogues". Chemistry of Materials. 19 (24): 5890–5901. doi:10.1021/cm071275h.

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